SDS Volume (2264)

Volume 59. Polycyclic Aromatic Hydrocarbons: Binary Non-aqueous Systems, Part II Solutes F-Z, p 78

Original Measurements

Mishra, D. S.; Yalkowsky, S. H.; Ind. Eng. Chem. Res.; 1990, 29, 2278-2283.

Variables:

Room Temp: 296 $\pu{K}$

Prepared by:

W.E. Acree, Jr.

Method/Apparatus/Procedure:

Constant temperature bath, rotator, thermometer, and an uv/visible spectrophotometer.
Excess solute and solvent placed in screw-capped test tube and allowed to equilibrate for three days with gentle agitation in a constant temperature bath. Samples centrifuged for 30 minutes and concentrations were determined spectrophotometically. Attainment of equilibrium verified by repetitive measurements four days later.

Source and Purity of Materials:
  1. Reagent grade, source not specified, was used as received.
  2. Reagent grade, source not specified, was used as received.
Estimated Errors:

Ambient temperature: T/K: ±0.1 (compiler). x1: ±5% (relative error; compiler).

Components:
  1. Naphthacene, $\ce{ C18H12 }$; [92-24-0] NIST WebBook
  2. Benzene, $\ce{ C6H6 }$; [71-43-2] NIST WebBook
Experimental Data
$T$ (°C) $x_{1}$ $x_{2}$
23.0 0.01430.9857

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