SDS Volume

Volume 59. Polycyclic Aromatic Hydrocarbons: Binary Non-aqueous Systems, Part II Solutes F-Z, p 69

Source Publication

Yokoyama, C.; Ebina, T.; Takahashi, S.; J. Chem. Eng. Data 1993, 38, 583-586.

Conditions:

Room Temp: Temperature $\pu{K}$

Compiler:

W.E. Acree, Jr.

Methodology:

Constant temperature bath and a precision thermometer.
Mixtures of known concentrations sealed in glass ampoules and placed in constant temperature to equilibrate. Samples were rotated while bath temperature slowly increased. Solubility determined by visual noting the same temperature at which the last trace of solid solute disappeared.

Sample Information:
  1. 99.9%, Aldrich Chemical Company, Milwaukee, Wisconsin, USA, was used as received.
  2. 99.9+%, Wako Pure Chemical Ind Ltd., was dried over molecular sieves prior to use.
Measurement Errors:

Ambient temperature: T/K: precision ±0.02. x1: ±0.0001.

System Components:
  1. Indole, $\ce{ C8H7N }$; [120-72-9] NIST WebBook
  2. 1-Methylnaphthalene, $\ce{ C11H10 }$; [90-12-0] NIST WebBook
Experimental Data
$T$ ($\pu{K}$) $x_{1}$ $x_{2}$
242.45 0.00001.0000
239.55 0.03400.9660
239.57 0.04140.9586
237.20 0.06920.9308
236.00 0.09120.9088
237.78 0.10270.8973
253.91 0.17080.8292
266.53 0.25600.7440
271.73 0.30200.6980
280.09 0.39520.6048
300.43 0.59520.4048
311.68 0.79820.2018
319.24 0.92270.0773
326.26 1.00000.0000

Authors report eutectic point occurs at x1 = 0.0946 and T/K = 235.31.

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