SDS Volume (2252)

Volume 59. Polycyclic Aromatic Hydrocarbons: Binary Non-aqueous Systems, Part II Solutes F-Z, p 9

Original Measurements

Kravchenko, V. M.; Pastukhova, I. S.; J. Gen. Chem. USSR 1959, 29, 29-34.

Variables:

Temperature: Temperature K

Prepared by:

W.E. Acree, Jr.

Method/Apparatus/Procedure:

Phase diagram was determined using a thermal analysis method [1], supplemented by visual observation.

Source and Purity of Materials:
  1. Purity and chemical source were not specified in paper, was recrystallized before use.
  2. Purity and chemical source were not specified in paper, was recrystallized before use.
References

1 Kravchenko, V. M.; Zh. Fiz. Khim. 1939, 13, 133-145.

Experimental Data

Fluoranthene with 2,7-Dimethylnaphthalene

Components:

(1) Fluoranthene, $\ce{ C16H10 }$; [206-44-0] NIST WebBook
(2) 2,7-Dimethylnaphthalene, $\ce{ C12H12 }$; [582-16-1] NIST WebBook

Experimental Values:
T (K)x1x2
370.2 0.0 1.0
365.3 8.4 x 10-2 9.16 x 10-1
358.1 2.08 x 10-1 7.92 x 10-1
352.6 2.96 x 10-1 7.04 x 10-1
344.2 4.28 x 10-1 5.72 x 10-1
339.2 4.82 x 10-1 5.18 x 10-1
340.7 5.09 x 10-1 4.91 x 10-1
349.3 5.93 x 10-1 4.07 x 10-1
356.4 6.72 x 10-1 3.28 x 10-1
363.8 7.58 x 10-1 2.42 x 10-1
372.6 8.64 x 10-1 1.36 x 10-1
383.2 1.0 0.0

Authors report eutectic point occurs at x1 = 0.482 and T/K = 339.2.

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