SDS Volume (2243)
Volume 59. Polycyclic Aromatic Hydrocarbons: Binary Non-aqueous Systems, Part II Solutes F-Z, p 59
Original Measurements
Shinomiya, C.; J. Chem. Soc. Japan 1940, 15, 259-270.
Variables:
Room Temp: Temperature $\pu{K}$
Prepared by:
Method/Apparatus/Procedure:
No experimental details given in paper.
Source and Purity of Materials:
- Purity and chemical source were not specified in paper.
- Purity and chemical source were not specified in paper.
Estimated Errors:
Ambient temperature: T/K: precision ±0.2 (compiler). x1: ±0.002 (compiler).
Components:
- Fluorene, $\ce{ C13H10 }$; [86-73-7] NIST WebBook
- 1,2,3,5-Tetranitrobenzene, $\ce{ C6H2N4O8 }$; [3698-53-1] NIST WebBook
Experimental Data
| $T$ ($\pu{K}$) | $x_{1}$ | $x_{2}$ |
|---|---|---|
| 399.2 | 0.000 | 1.000 |
| 393.7 | 0.097 | 0.903 |
| 398.2 | 0.176 | 0.824 |
| 402.2 | 0.275 | 0.725 |
| 403.2 | 0.326 | 0.674 |
| 403.2 | 0.351 | 0.649 |
| 402.2 | 0.394 | 0.606 |
| 402.7 | 0.398 | 0.602 |
| 401.5 | 0.457 | 0.543 |
| 397.7 | 0.550 | 0.450 |
| 381.2 | 0.728 | 0.272 |
| 370.2 | 0.769 | 0.231 |
| 373.4 | 0.830 | 0.170 |
| 382.2 | 0.914 | 0.086 |
| 389.2 | 1.000 | 0.000 |
Authors reports formations of a 1:2 fluorene - 1,2,3,5-tetranitrobenzene orangish-red compound having a melting point temperature of 403.2 K. Two eutectic points occur at x1 = 0.120 and T/K = 390.7, and at x1 = 0.780 and T/K = 364.2.
