Compilation - Fluorene with 1,3-Dinitrobenzene (IUPAC SDS Volume 59)
SDS Volume (2239)
Volume 59. Polycyclic Aromatic Hydrocarbons: Binary Non-aqueous Systems, Part II Solutes F-Z, p 56
Original Measurements
Kremann, R.; Monatsch. Chem. 1911, 32, 609-617.
Variables:
Room Temp: Temperature $\pu{K}$
Prepared by:
Method/Apparatus/Procedure:
Binary mixtures prepared by weight. While the experimental details were not given in the paper, compiler speculates (based upon quantity of material used) that the sample was sealed in a glass container, temperature slowly varied, and the phase diagram determined by visually noting the temperature at which the last/first crystal of solid disappeared/appeared.
Source and Purity of Materials:
- Purity and chemical source were not specified in paper.
- Purity and chemical source were not specified in paper.
Estimated Errors:
Ambient temperature: T/K: precision ±0.2 (compiler). x1: ±0.002 (compiler).
Components:
- Fluorene, $\ce{ C13H10 }$; [86-73-7] NIST WebBook
- 1,3-Dinitrobenzene, $\ce{ C6H4N2O4 }$; [99-65-0] NIST WebBook
Experimental Data
| $T$ ($\pu{K}$) | $x_{1}$ | $x_{2}$ |
|---|---|---|
| 362.2 | 0.000 | 1.000 |
| 357.7 | 0.071 | 0.929 |
| 352.7 | 0.163 | 0.837 |
| 345.7 | 0.236 | 0.764 |
| 339.7 | 0.328 | 0.672 |
| 332.2 | 0.394 | 0.606 |
| 329.2 | 0.421 | 0.579 |
| 332.7 | 0.453 | 0.547 |
| 338.2 | 0.489 | 0.511 |
| 341.7 | 0.515 | 0.485 |
| 345.7 | 0.534 | 0.466 |
| 350.7 | 0.585 | 0.415 |
| 356.2 | 0.630 | 0.370 |
| 362.7 | 0.685 | 0.315 |
| 365.2 | 0.740 | 0.260 |
| 374.7 | 0.848 | 0.152 |
| 378.2 | 0.896 | 0.104 |
| 382.2 | 0.950 | 0.050 |
| 385.7 | 1.000 | 0.000 |
