Compilation - Fluoranthene with Naphthalene (IUPAC SDS Volume 59)
SDS Volume (2230)
Volume 59. Polycyclic Aromatic Hydrocarbons: Binary Non-aqueous Systems, Part II Solutes F-Z, p 7
Original Measurements
Kravchenko, V. M.; Pastukhova, I. S.; J. Gen. Chem. USSR 1959, 29, 29-34.
Variables:
Room Temp: Temperature $\pu{K}$
Prepared by:
Method/Apparatus/Procedure:
Phase diagram was determined using a thermal analysis method [1], supplemented by visual observation.
Source and Purity of Materials:
- Purity and chemical source were not specified in paper, was recrystallized before use.
- Purity and chemical source were not specified in paper, was recrystallized before use.
Estimated Errors:
Ambient temperature: T/K: precision ±0.2. x1: ±0.002 (compiler).
References
1 Kravchenko, V. M.; Zh. Fiz. Khim. 1939, 13, 133-145.
Components:
- Fluoranthene, $\ce{ C16H10 }$; [206-44-0] NIST WebBook
- Naphthalene, $\ce{ C10H8 }$; [91-20-3] NIST WebBook
Experimental Data
| $T$ ($\pu{K}$) | $x_{1}$ | $x_{2}$ |
|---|---|---|
| 353.4 | 0.000 | 1.000 |
| 346.3 | 0.117 | 0.883 |
| 338.5 | 0.247 | 0.753 |
| 332.2 | 0.337 | 0.663 |
| 329.0 | 0.390 | 0.610 |
| 330.9 | 0.411 | 0.589 |
| 337.1 | 0.461 | 0.539 |
| 343.5 | 0.519 | 0.471 |
| 352.8 | 0.614 | 0.386 |
| 361.4 | 0.707 | 0.293 |
| 374.2 | 0.875 | 0.125 |
| 383.2 | 1.000 | 0.000 |
Authors report eutectic point occurs at x1 = 0.390 and T/K = 329.0.
