Compilation - Fluorene with Fluoranthene (IUPAC SDS Volume 59)
SDS Volume (2224)
Volume 59. Polycyclic Aromatic Hydrocarbons: Binary Non-aqueous Systems, Part II Solutes F-Z, p 47
Original Measurements
Kravchenko, V. M.; J. Appl. Chem. USSR 1952, 25, 1015-1022.
Variables:
Room Temp: Temperature $\pu{K}$
Prepared by:
Method/Apparatus/Procedure:
Phase diagram was determined using a thermal analysis method [1], supplemented by visual observation.
Source and Purity of Materials:
- Purity and chemical source were not specified in paper, was recrystallized before use.
- Purity and chemical source were not specified in paper, was recrystallized before use.
Estimated Errors:
Ambient temperature: T/K: precision ±0.2. x1: ±0.002 (compiler).
References
1 Kravchenko, V. M.; Zh. Fiz. Khim. 1939, 13, 133-145.
Components:
- Fluorene, $\ce{ C13H10 }$; [86-73-7] NIST WebBook
- Fluoranthene, $\ce{ C16H10 }$; [206-44-0] NIST WebBook
Experimental Data
| $T$ ($\pu{K}$) | $x_{1}$ | $x_{2}$ |
|---|---|---|
| 383.2 | 0.000 | 1.000 |
| 376.3 | 0.095 | 0.905 |
| 368.1 | 0.203 | 0.797 |
| 360.0 | 0.296 | 0.704 |
| 352.6 | 0.375 | 0.625 |
| 347.9 | 0.429 | 0.571 |
| 343.1 | 0.470 | 0.530 |
| 342.2 | 0.481 | 0.519 |
| 345.3 | 0.523 | 0.477 |
| 353.8 | 0.611 | 0.389 |
| 363.7 | 0.702 | 0.298 |
| 373.2 | 0.805 | 0.195 |
| 380.7 | 0.901 | 0.099 |
| 387.2 | 1.000 | 0.000 |
Authors report eutectic point occurs at x2 = 0.519 and T/K = 342.2.
