SDS Volume (2210)

Volume 59. Polycyclic Aromatic Hydrocarbons: Binary Non-aqueous Systems, Part II Solutes F-Z, p None

Original Measurements

Coon, J. E.; Auwaerter, J. E.; McLaughlin, E.; Fluid Phase Equilib. 1989, 44, 305-345.

Variables:

Room Temp: Temperature $\pu{K}$

Prepared by:

W.E. Acree, Jr.

Method/Apparatus/Procedure:

Constant temperature bath and a precision thermometer.
Mixtures of known concentrations sealed in glass ampoules and placed in constant temperature to equilibrate. Samples were rotated while bath temperature slowly increased. Solubility determined by visual noting the temperature at which the last trace of solid solute disappeared.

Source and Purity of Materials:
  1. 99.65%, Aldrich Chemical Company, Milwaukee, Wisconsin, USA, was used as received.
  2. 99.6+%, Aldrich Chemical Company, was stored over molecular sieves to remove trace water.
Estimated Errors:

Ambient temperature: T/K: precision ±0.1. x1: ±0.0003.

Components:
  1. Xanthene, $\ce{ C13H10O }$; [92-83-1] NIST WebBook
  2. 1,2,3,4-Tetrahydronaphthalene, $\ce{ C10H12 }$; [119-64-2] NIST WebBook
Experimental Data
$T$ ($\pu{K}$) $x_{1}$ $x_{2}$
304.6 0.22020.7798
318.3 0.28760.7124
331.8 0.40220.5978
340.9 0.50140.4986
348.9 0.60470.3953
349.9 0.62860.3714

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