Compilation - Bromobenzene with Water (IUPAC SDS Volume 20)
SDS Volume (22)
Volume 20. Halogenated Benzenes, Toluenes and Phenols with Water, p 138
Original Measurements
Bell, R. P.; J. Chem. Soc. 1932, 2905-11.
Variables:
Room Temp: 15, 20, and 25 °C
Prepared by:
Method/Apparatus/Procedure:
About 1 to 5 ratio solute/solvent mixtures were rotated in a thermostat bath for 12 hrs. After equilibrium was established, samples were taken and filtered through cotton wool. The determination of the water content was based on the reaction with o-naphthoxydichlorophosphine. The evolved $\ce{HCl}$ was absorbed in water and titrated with $\ce{NaOH}$ solution [1]. Successive (2-4) determinations were carried out with the solvent.
Source and Purity of Materials:
- Distilled (compiler).
- Merck reagent, analytical grade, redistilled before use.
Estimated Errors:
Ambient temperature: ±0.02 K.
Mass concentration (m/v) (1): ±2.6%.
References
Components:
- Bromobenzene, $\ce{ C6H5Br }$; [108-86-1] NIST WebBook
- Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook
Experimental Data
| $T$ (°C) | $x_{1}$ | $C_{1}$ (mol/dm3) |
|---|---|---|
| 15 | 1.443 x 10-3 | 0.01382 |
| 20 | 1.781 x 10-3 | 0.01698 |
| 25 | 2.186 x 10-3 | 0.02075 |
(c) Calculated by the compiler.
(a) Reported.
(b) Calculated by F. W. Getzen.
