Compilation - Thianthrene with Phenoxazine (IUPAC SDS Volume 59)
SDS Volume (2196)
Volume 59. Polycyclic Aromatic Hydrocarbons: Binary Non-aqueous Systems, Part II Solutes F-Z, p None
Original Measurements
Cullinane, N. M.; Rees, W. T.; Trans. Faraday Soc. 1940, 36, 506-514.
Variables:
Room Temp: Temperature $\pu{K}$
Prepared by:
Method/Apparatus/Procedure:
Mixtures were placed in small capillary tubes. Temperature was slowly varied with ample time given for equilibration. Transition temperatures determined by visual observations. Reported temperatures verified by repetitive measurements.
Source and Purity of Materials:
- Purity and chemical source were not specified in paper, was purified by sublimation and recrystallization from acetone.
- Synthesized by authors, and was purified by recrystallization from alcohol and sublimation.
Estimated Errors:
Ambient temperature: T/K: ±precision 0.2 (compiler). x1: ±0.002 (compiler).
Components:
- Thianthrene, $\ce{ C12H8S2 }$; [92-85-3] NIST WebBook
- Phenoxazine, $\ce{ C12H8NO }$; [135-67-1] NIST WebBook
Experimental Data
| $T$ ($\pu{K}$) | $x_{1}$ | $x_{2}$ |
|---|---|---|
| 429.9 | 0.000 | 1.000 |
| 428.1 | 0.033 | 0.967 |
| 412.2 | 0.341 | 0.659 |
| 393.4 | 0.439 | 0.561 |
| 392.0 | 0.458 | 0.542 |
| 399.4 | 0.531 | 0.469 |
| 416.4 | 0.749 | 0.251 |
| 427.5 | 0.946 | 0.054 |
| 429.9 | 1.000 | 0.000 |
