Compilation - Thianthrene with Phenoxanthiin (IUPAC SDS Volume 59)
SDS Volume (2195)
Volume 59. Polycyclic Aromatic Hydrocarbons: Binary Non-aqueous Systems, Part II Solutes F-Z, p None
Original Measurements
Cullinane, N. M.; Rees, W. T.; Trans. Faraday Soc. 1940, 36, 506-514.
Variables:
Room Temp: Temperature $\pu{K}$
Prepared by:
Method/Apparatus/Procedure:
Mixtures were placed in small capillary tubes. Temperature was slowly varied with ample time given for equilibration. Transition temperatures determined by visual observations. Reported temperatures verified by repetitive measurements.
Source and Purity of Materials:
- Purity and chemical source not specified, was purified by sublimation and recrystallized from acetone.
- Synthesized by authors, was purified by sublimation and recrystallized from alcohol.
Estimated Errors:
Ambient temperature: T/K: ±precision 0.2 (compiler). x1: ±0.002 (compiler).
Components:
- Thianthrene, $\ce{ C12H8S2 }$; [92-85-3] NIST WebBook
- Phenoxanthiin, $\ce{ C12H8OS }$; [262-20-4] NIST WebBook
Experimental Data
| $T$ ($\pu{K}$) | $x_{1}$ | $x_{2}$ |
|---|---|---|
| 328.9 | 0.000 | 1.000 |
| 328.3 | 0.046 | 0.954 |
| 326.1 | 0.070 | 0.930 |
| 337.2 | 0.100 | 0.900 |
| 357.4 | 0.189 | 0.811 |
| 378.7 | 0.308 | 0.692 |
| 399.5 | 0.513 | 0.487 |
| 415.3 | 0.699 | 0.301 |
| 426.8 | 0.900 | 0.100 |
| 429.9 | 1.000 | 0.000 |
