SDS Volume
Volume 59. Polycyclic Aromatic Hydrocarbons: Binary Non-aqueous Systems, Part II Solutes F-Z, p None
Source Publication
Zvaignze, A. I.; Acree Jr., W. E.; J. Chem. Eng. Data 1993, 38, 393-395.
Conditions:
Room Temp: 299 $\pu{K}$
Compilers:
W.E. Acree, Jr., A.I. Zvaigzne
Methodology:
Constant temperature bath, calorimetric thermometer, and an ultraviolet/visible spectrophotometer.
Binary solvent mixtures were prepared by weight. Excess solute and solvent placed in amber glass bottles and allowed to equilibrate for several days at constant temperature. Attainment of equilibrium was verified by several repetitive measurements and by approaching equilibrium from supersaturation. Aliquots of saturated solutions transferred through a coarse filter into tared volumetric flasks, weighed and diluted with methanol. Concentrations determined spectrophotometrically at 372 nm.
Sample Information:
- 99%, Aldrich Chemical Company, Milwaukee, Wisconsin, USA, recrystallized three times from absolute ethanol.
- HPLC Grade, 99.7+%, Aldrich Chemical Company.
- 99+%, anhydrous, Aldrich Chemical Company. Components (2) and (3) were stored over molecular sieves and distilled shortly before use.
Measurement Errors:
Ambient temperature: T/K: ±0.05. x3(s): ±0.0001. x1: 1.5% (relative error).
System Components:
- Pyrene, $\ce{ C16H10 }$; [129-00-0] NIST WebBook
- 2,2,4-Trimethylpentane, $\ce{ C8H18 }$; [540-84-1] NIST WebBook
- 1-Propanol, $\ce{ C3H8O }$; [71-23-8] NIST WebBook
Experimental Data
| $T$ (°C) | $x^{\rm{init}}_{3}$ | $x_{1}$ | $x_{3}$ |
|---|---|---|---|
| 26.0 | 0.0000 | 7.20 x 10-3 | 0.0000 |
| 26.0 | 0.2131 | 7.38 x 10-3 | 0.2115 |
| 26.0 | 0.3581 | 7.21 x 10-3 | 0.3555 |
| 26.0 | 0.5925 | 6.59 x 10-3 | 0.5886 |
| 26.0 | 0.6783 | 6.24 x 10-3 | 0.6741 |
| 26.0 | 0.7710 | 5.84 x 10-3 | 0.7665 |
| 26.0 | 0.8887 | 5.11 x 10-3 | 0.8842 |
| 26.0 | 0.9421 | 4.72 x 10-3 | 0.9377 |
| 26.0 | 1.0000 | 4.26 x 10-3 | 0.9957 |
x3(s): initial mole fraction of binary solvent mixture; x1: mole fraction solubility of the solute; x3: mole fraction of component 3 in the ternary solution.
