SDS Volume
Volume 59. Polycyclic Aromatic Hydrocarbons: Binary Non-aqueous Systems, Part II Solutes F-Z, p None
Source Publication
Bando, M.; Matsunaga, Y.; Bull. Chem. Soc. Japan 1976, 49, 3345-3346.
Conditions:
Room Temp: N/A
Compiler:
Methodology:
Differential scanning calorimeter.
Binary mixtures were prepared by weight. Melting points and transition temperatures determined using a differential scanning calorimeter.
An experimental phase diagram is given in the original paper.
Sample Information:
- Purity and chemical source were not specified in paper.
- Purity and chemical source were not specified in paper.
Measurement Errors:
Ambient temperature: T/K: precision ±0.1 (compiler). x1: ±0.002 (compiler).
System Components:
- Pyrene, $\ce{ C16H10 }$; [129-00-0] NIST WebBook
- 2-Chloro-1,3,5-trinitrobenzene, $\ce{ C6H2ClN3O6 }$; [88-88-0] NIST WebBook
Experimental Data
Authors report formation of a 1:1 pyrene - 2-chloro-1,3,5-trinitrobenzene molecular compound having a melting point of 427.2 K. An eutectic point occurs at x1 = 0.120 and T/K = 348.2. Four incongruently melting pyrene - 2-chloro-1,3,5-trinitrobenzene compounds with 4:3, 2:1, 3:1 and 4:1 stoichoimetries were also reported to exist.
