SDS Volume
Volume 59. Polycyclic Aromatic Hydrocarbons: Binary Non-aqueous Systems, Part II Solutes F-Z, p None
Source Publication
Krajewska, A.; Wasilewska, K.; Thermochim. Acta 1981, 44, 117-120.
Conditions:
Room Temp: N/A
Compiler:
Methodology:
Differential scanning calorimeter and thermostated light microscope.
Binary mixtures were prepared by weight. Melting point temperatures and phase diagram determined using differential scanning calorimetric and microscopic techniques.
Sample Information:
- Purity and chemical source were not specified in paper.
- Purity and chemical source were not specified in paper.
Measurement Errors:
Ambient temperature: T/K: precision ±0.1 (compiler). x1: ±0.002 (compiler).
System Components:
- Pyrene, $\ce{ C16H10 }$; [129-00-0] NIST WebBook
- 2-Chloro-1,3,5-trinitrobenzene, $\ce{ C6H2ClN3O6 }$; [88-88-0] NIST WebBook
Experimental Data
Authors report that the binary system exhibits a fairly simple phase diagram. A 1:1 pyrene - 2-chloro-1,3,5-trinitrobenzene molecular compound with melting point of T/K - 429, and an incongruently melting 3:2 pyrene - 2-chloro-1,3,5-trinitrobenzene molecular compound were observed.
