SDS Volume
Volume 59. Polycyclic Aromatic Hydrocarbons: Binary Non-aqueous Systems, Part II Solutes F-Z, p None
Source Publication
Shinomiya, C.; J. Chem. Soc. Japan 1940, 15, 259-270.
Conditions:
Room Temp: Temperature $\pu{K}$
Compiler:
Methodology:
No experimental details given in paper.
Sample Information:
- Purity and chemical source were not specified in paper.
- Purity and chemical source were not specified in paper.
Measurement Errors:
Ambient temperature: T/K: precision ±0.2 (compiler). x1: ±0.002 (compiler).
System Components:
- Pyrene, $\ce{ C16H10 }$; [129-00-0] NIST WebBook
- 2,4,6-Trinitromethoxybenzene, $\ce{ C7H5N3O7 }$; [606-35-9] NIST WebBook
Experimental Data
| $T$ ($\pu{K}$) | $x_{1}$ | $x_{2}$ |
|---|---|---|
| 341.2 | 0.000 | 1.000 |
| 356.2 | 0.133 | 0.867 |
| 365.2 | 0.204 | 0.796 |
| 365.7 | 0.218 | 0.782 |
| 373.2 | 0.340 | 0.660 |
| 376.2 | 0.431 | 0.569 |
| 377.2 | 0.468 | 0.532 |
| 377.7 | 0.529 | 0.471 |
| 377.7 | 0.624 | 0.376 |
| 385.2 | 0.654 | 0.346 |
| 401.2 | 0.778 | 0.222 |
| 413.7 | 0.875 | 0.125 |
| 423.2 | 1.000 | 0.000 |
Author reports formation of a 1:1 pyrene - 2,4,6-trinitromethoxybenzene yellowish-orange molecular compound having a melting point temperature of 377.7 K. Two eutectic points occur at x1 = 0.030 and T/K = 333.7, and at x1 = 0.605 and T/K = 371.7.
