SDS Volume (2160)
Volume 59. Polycyclic Aromatic Hydrocarbons: Binary Non-aqueous Systems, Part II Solutes F-Z, p None
Original Measurements
Shinomiya, C.; J. Chem. Soc. Japan 1940, 15, 259-270.
Variables:
Temperature: Temperature K
Prepared by:
Method/Apparatus/Procedure:
No experimental details given in paper.
Source and Purity of Materials:
- Purity and chemical source were not specified in paper.
- Purity and chemical source were not specified in paper.
Experimental Data
Pyrene with 1,2,3,5-Tetranitrobenzene
Components:
(1) Pyrene,
$\ce{ C16H10 }$;
[129-00-0]
NIST WebBook
(2) 1,2,3,5-Tetranitrobenzene,
$\ce{ C6H2N4O8 }$;
[3698-53-1]
NIST WebBook
Experimental Values:
| T (K) | x1 | x2 |
|---|---|---|
| 399.2 | 0.0 | 1.0 |
| 398.2 | 9.6 x 10-2 | 9.04 x 10-1 |
| 435.2 | 3.39 x 10-1 | 6.61 x 10-1 |
| 439.7 | 4.06 x 10-1 | 5.94 x 10-1 |
| 441.2 | 4.90 x 10-1 | 5.10 x 10-1 |
| 441.2 | 4.97 x 10-1 | 5.03 x 10-1 |
| 435.2 | 5.94 x 10-1 | 4.06 x 10-1 |
| 431.2 | 6.20 x 10-1 | 3.80 x 10-1 |
| 414.2 | 7.49 x 10-1 | 2.51 x 10-1 |
| 400.2 | 7.95 x 10-1 | 2.05 x 10-1 |
| 403.2 | 8.38 x 10-1 | 1.62 x 10-1 |
| 420.2 | 9.58 x 10-1 | 4.2 x 10-2 |
| 423.2 | 1.0 | 0.0 |
Author reports formation of a 1:1 pyrene - 1,2,3,5-tetranitrobenzene dark red molecular compound having a melting point temperature of 441.7 K. Two eutectic points occur at x1 = 0.085 and T/K = 395.2, and at x1 = 0.810 and T/K = 398.2.
