Components:
(1) Pyrene,
C16H10; [129-00-0]
NIST WebBook
(2) 1,3,5-Trinitrobenzene,
C6H6N3O6; [99-35-4]
NIST WebBook
Original Measurements
Shinomiya, C.; J. Chem. Soc. Japan 1940, 15, 259-270.
Variables:
Ambient temperature: Temperature
Prepared by:
Method/Apparatus/Procedure:
No experimental details given in paper.
Source and Purity of Materials:
- Purity and chemical source were not specified in paper.
- Purity and chemical source were not specified in paper.
Estimated Errors:
Ambient temperature: T/K: precision ±0.2 (compiler). x1: ±0.002 (compiler).
Experimental Values:
| T (K) | x1 | x2 |
|---|---|---|
| 396.2 | 0.0 | 1.0 |
| 420.2 | 5.0 x 10-2 | 9.50 x 10-1 |
| 478.2 | 1.72 x 10-1 | 8.28 x 10-1 |
| 478.2 | 1.74 x 10-1 | 8.26 x 10-1 |
| 500.2 | 2.60 x 10-1 | 7.40 x 10-1 |
| 514.7 | 3.73 x 10-1 | 6.27 x 10-1 |
| 518.7 | 4.86 x 10-1 | 5.14 x 10-1 |
| 517.2 | 5.53 x 10-1 | 4.47 x 10-1 |
| 508.7 | 6.79 x 10-1 | 3.21 x 10-1 |
| 482.5 | 7.78 x 10-1 | 2.22 x 10-1 |
| 466.7 | 8.40 x 10-1 | 1.60 x 10-1 |
| 439.2 | 8.75 x 10-1 | 1.25 x 10-1 |
| 423.2 | 1.0 | 0.0 |
(None) Author reports formation of a 1:1 pyrene - 1,3,5-trinitrobenzene reddish-orange molecular compound having a melting point temperature of 518.7 K. Two eutectic points occur at x1 = 0.020 and T/K = 389.2, and at x1 = 0.900 and T/K = 414.7.
