SDS Volume (2134)

Volume 59. Polycyclic Aromatic Hydrocarbons: Binary Non-aqueous Systems, Part II Solutes F-Z, p None

Original Measurements

Pinal, R.; Rao, P. S. C.; Lee, L. S.; Cline, P. V.; Yalkowsky, S. H.; Environ. Sci. Technol. 1990, 24, 639-647.

Variables:

Temperature: 296 K

Prepared by:

W.E. Acree, Jr.

Method/Apparatus/Procedure:

Constant temperature bath, centrifuge, thermometer, and an HPLC equipped with uv absorption and fluorescence detection.
Excess solute and solvent were placed in glass vials and allowed to equilibrate with rotation for 12-24 hours in a constant temperature bath. Prior to analysis samples were centrifuged at a minimum of 300 RCF for 15 minutes. The clear supernatant solution was analyzed by reversed phase liquid chromatography with either fluorescence or uv detection.

Source and Purity of Materials:
  1. Purity not given, commercial sample of unspecified source, was used as received.
  2. Purity and chemical source not given, purification procedure not specified.
Experimental Data

Pyrene with Methanol

Components:

(1) Pyrene, $\ce{ C16H10 }$; [129-00-0] NIST WebBook
(2) Methanol, $\ce{ CH4O }$; [67-56-1] NIST WebBook

Experimental Values:
T (°C)C1 (mol/dm3)
23.0 6.73 x 10-2

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