SDS Volume (2125)
Volume 59. Polycyclic Aromatic Hydrocarbons: Binary Non-aqueous Systems, Part II Solutes F-Z, p 31
Original Measurements
Shinomiya, C.; J. Chem. Soc. Japan 1940, 15, 259-270.
Variables:
Room Temp: Temperature $\pu{K}$
Prepared by:
Method/Apparatus/Procedure:
No experimental details given in paper.
Source and Purity of Materials:
- Purity and chemical source were not specified in paper.
- Purity and chemical source were not specified in paper.
Estimated Errors:
Ambient temperature: T/K: ±precision 0.2. (compiler). x1: ±0.002 (compiler).
Components:
- Fluoranthene, $\ce{ C16H10 }$; [206-44-0] NIST WebBook
- 3-Methyl-2,4,6-trinitrophenol, $\ce{ C7H5N3O7 }$; [602-99-3] NIST WebBook
Experimental Data
| $T$ ($\pu{K}$) | $x_{1}$ | $x_{2}$ |
|---|---|---|
| 381.7 | 0.000 | 1.000 |
| 383.2 | 0.110 | 0.890 |
| 412.2 | 0.323 | 0.677 |
| 416.2 | 0.431 | 0.569 |
| 417.2 | 0.517 | 0.483 |
| 416.2 | 0.568 | 0.432 |
| 412.2 | 0.636 | 0.364 |
| 399.7 | 0.786 | 0.214 |
| 385.2 | 0.862 | 0.138 |
| 378.2 | 0.883 | 0.117 |
| 381.0 | 0.962 | 0.038 |
| 382.7 | 1.000 | 0.000 |
Authors reports formations of a 1:1 fluoranthene - 3-methyl-2,4,6-trinitrophenol yellow compound having a melting point of 417.2 K. Two eutectic points occur at x1 = 0.082 and T/K = 374.2, and at x1 = 0.890 and T/K = 374.2.
