SDS Volume
Volume 59. Polycyclic Aromatic Hydrocarbons: Binary Non-aqueous Systems, Part II Solutes F-Z, p 29
Source Publication
Shinomiya, C.; J. Chem. Soc. Japan 1940, 15, 259-270.
Conditions:
Room Temp: Temperature $\pu{K}$
Compiler:
Methodology:
No experimental details given in paper.
Sample Information:
- Purity and chemical source were not specified in paper.
- Purity and chemical source were not specified in paper.
Measurement Errors:
Ambient temperature: T/K: ±precision 0.2. (compiler). x1: ±0.002 (compiler).
System Components:
- Fluoranthene, $\ce{ C16H10 }$; [206-44-0] NIST WebBook
- 2,4,6-Trinitroaniline, $\ce{ C6H4N4O6 }$; [489-98-5] NIST WebBook
Experimental Data
| $T$ ($\pu{K}$) | $x_{1}$ | $x_{2}$ |
|---|---|---|
| 461.7 | 0.000 | 1.000 |
| 444.7 | 0.223 | 0.777 |
| 453.7 | 0.352 | 0.648 |
| 464.2 | 0.485 | 0.515 |
| 464.2 | 0.518 | 0.482 |
| 460.7 | 0.616 | 0.384 |
| 459.2 | 0.648 | 0.352 |
| 441.2 | 0.738 | 0.262 |
| 414.2 | 0.842 | 0.158 |
| 390.7 | 0.901 | 0.099 |
| 378.2 | 0.947 | 0.053 |
| 382.7 | 1.000 | 0.000 |
Authors reports formations of a 1:1 fluoranthene - 2,4,6-trinitroaniline brownish-yellow compound having a melting point temperature of 464.7 K. Two eutectic points occur at x1 = 0.267 and T/K = 439.2, and at x1 = 0.928 and T/K = 375.2.
