SDS Volume
Volume 59. Polycyclic Aromatic Hydrocarbons: Binary Non-aqueous Systems, Part II Solutes F-Z, p 27
Source Publication
Shinomiya, C.; J. Chem. Soc. Japan 1940, 15, 259-270.
Conditions:
Room Temp: Temperature $\pu{K}$
Compiler:
Methodology:
No experimental details given in paper.
Sample Information:
- Purity and chemical source were not specified in paper.
- Purity and chemical source were not specified in paper.
Measurement Errors:
Ambient temperature: T/K: ±precision 0.2 (compiler). x1: ±0.002 (compiler).
System Components:
- Fluoranthene, $\ce{ C16H10 }$; [206-44-0] NIST WebBook
- 2,4,6-Trinitro-1-methylbenzene, $\ce{ C7H5N3O6 }$; [118-96-7] NIST WebBook
Experimental Data
| $T$ ($\pu{K}$) | $x_{1}$ | $x_{2}$ |
|---|---|---|
| 354.7 | 0.000 | 1.0000 |
| 368.2 | 0.208 | 0.792 |
| 387.2 | 0.292 | 0.708 |
| 399.2 | 0.361 | 0.639 |
| 405.2 | 0.433 | 0.567 |
| 404.7 | 0.557 | 0.443 |
| 405.2 | 0.564 | 0.436 |
| 386.2 | 0.715 | 0.285 |
| 380.2 | 0.737 | 0.263 |
| 363.2 | 0.788 | 0.212 |
| 373.4 | 0.862 | 0.138 |
| 382.7 | 1.000 | 0.000 |
Authors reports formations of a 1:1 fluoranthene - 2,4,6-trinitromethylbenzene yellow compound having a melting point temperature of 406.2 K. Two eutectic points occur at x1 = 0.150 and T/K = 345.7, and at x1 = 0.788 and T/K = 362.2.
