Compilation - Phenanthrene with Dibenzothiophene (IUPAC SDS Volume 59)
SDS Volume (2073)
Volume 59. Polycyclic Aromatic Hydrocarbons: Binary Non-aqueous Systems, Part II Solutes F-Z, p None
Original Measurements
Burger, A.; Bryant, H. W.; J. Am. Chem. Soc. 1941, 63, 1054-1057.
Variables:
Room Temp: 177.7 - 346.4 $\pu{K}$
Prepared by:
Method/Apparatus/Procedure:
No experimental details given in paper.
Source and Purity of Materials:
- Purity and chemical source were not specified in paper.
- Purity and chemical source were not specified in paper.
Estimated Errors:
Ambient temperature: T/K: ±precision 0.2 (compiler). x1: ±0.01 (compiler).
Components:
- Phenanthrene, $\ce{ C14H10 }$; [85-01-8] NIST WebBook
- Dibenzothiophene, $\ce{ C12H8S }$; [132-65-0] NIST WebBook
Experimental Data
Experimentally determined phase diagram, which is depicted graphically in the original paper, shows phenanthrene + dibenzothiophene mixtures to form a simple eutectic system. The eutectic point occurs at circa x2 = 0.52 and T/K = 349.
