SDS Volume (2059)
Volume 59. Polycyclic Aromatic Hydrocarbons: Binary Non-aqueous Systems, Part II Solutes F-Z, p 25
Original Measurements
Shinomiya, C.; J. Chem. Soc. Japan 1940, 15, 259-270.
Variables:
Room Temp: Temperature $\pu{K}$
Prepared by:
Method/Apparatus/Procedure:
No experimental details given in paper.
Source and Purity of Materials:
- Purity and chemical source were not specified in paper.
- Purity and chemical source were not specified in paper.
Estimated Errors:
Ambient temperature: T/K: ±precision 0.2. (compiler). x1: ±0.002 (compiler).
Components:
- Fluoranthene, $\ce{ C16H10 }$; [206-44-0] NIST WebBook
- 2,4-Dinitro-1-methylbenzene, $\ce{ C7H6N2O4 }$; [121-14-2] NIST WebBook
Experimental Data
| $T$ ($\pu{K}$) | $x_{1}$ | $x_{2}$ |
|---|---|---|
| 344.2 | 0.000 | 1.000 |
| 341.2 | 0.059 | 0.941 |
| 336.2 | 0.147 | 0.853 |
| 332.2 | 0.230 | 0.770 |
| 334.2 | 0.253 | 0.747 |
| 338.7 | 0.305 | 0.695 |
| 342.7 | 0.364 | 0.636 |
| 346.7 | 0.448 | 0.552 |
| 347.7 | 0.457 | 0.543 |
| 348.7 | 0.548 | 0.452 |
| 347.2 | 0.598 | 0.402 |
| 347.7 | 0.779 | 0.221 |
| 363.2 | 0.802 | 0.198 |
| 375.7 | 0.910 | 0.090 |
| 382.7 | 1.000 | 0.000 |
Authors reports formations of a 1:1 fluoranthene - 2,4-dinitromethylbenzene yellow molecular compound having a melting point temperature of 348.7 K. Two eutectic points occur at x1 = 0.224 and T/K = 330.2, and at x1 = 0.640 and T/K = 341.2.
