Compilation - Phenanthrene with 1,1,1,2,2,3,3,4,4,5,5,6,6,7,7-pentadecafluoroheptane (IUPAC SDS Volume 59)
SDS Volume (2049)
Volume 59. Polycyclic Aromatic Hydrocarbons: Binary Non-aqueous Systems, Part II Solutes F-Z, p None
Original Measurements
McLaughlin, E.; Scott, R. L.; J. Phys. Chem. 1956, 60, 674-676.
Variables:
Room Temp: 298 $\pu{K}$
Prepared by:
Method/Apparatus/Procedure:
Constant temperature bath, a precision thermometer and uv/visible spectrometer.
Mixtures of known concentrations sealed in glass ampoules and allowed to equilibrate at a constant temperature for an unspecified length of time. Solubilities calculated from spectral absorbance data at 270 nm.
Source and Purity of Materials:
- White Label, Eastman Kodak Company, Rochester, New York, USA, was recrystallized ten times from ethanol.
- Purity not specified, synthesized by authors, was fractionally distilled shortly before use.
Estimated Errors:
Ambient temperature: T/K: precision ±0.01. x1: ±3% (relative error; compiler).
Components:
- Phenanthrene, $\ce{ C14H10 }$; [85-01-8] NIST WebBook
- 1-Hydropentadecafluoroheptane, $\ce{ C7HF15 }$; [375-83-7] NIST WebBook
Experimental Data
| $T$ (°C) | $x_{1}$ | $x_{2}$ |
|---|---|---|
| 25.0 | 1.60 x 10-3 | 0.9984 |


