Compilation - Phenanthrene with Fluoroanthene (IUPAC SDS Volume 59)
SDS Volume (2044)
Volume 59. Polycyclic Aromatic Hydrocarbons: Binary Non-aqueous Systems, Part II Solutes F-Z, p None
Original Measurements
Kravchenko, V. M.; Pastukhova, I. S.; J. Gen. Chem. USSR 1959, 29, 29-34.
Variables:
Room Temp: Temperature $\pu{K}$
Prepared by:
Method/Apparatus/Procedure:
Phase diagram was determined using a thermal analysis method [1], supplemented by visual observation.
Source and Purity of Materials:
- Purity and chemical source were not specified in paper, was recrystallized before use.
- Purity and chemical source were not specified in paper, was recrystallized before use.
Estimated Errors:
Ambient temperature: T/K: precision ±0.2. x1: ±0.002 (compiler).
References
1 Kravchenko, V. M.; Zh. Fiz. Khim. 1939, 13, 133-145.
Components:
- Phenanthrene, $\ce{ C14H10 }$; [85-01-8] NIST WebBook
- Fluoranthene, $\ce{ C16H10 }$; [206-44-0] NIST WebBook
Experimental Data
| $T$ ($\pu{K}$) | $x_{1}$ | $x_{2}$ |
|---|---|---|
| 383.2 | 0.000 | 1.000 |
| 375.7 | 0.104 | 0.896 |
| 365.0 | 0.262 | 0.738 |
| 358.5 | 0.356 | 0.644 |
| 353.4 | 0.437 | 0.563 |
| 347.5 | 0.520 | 0.480 |
| 346.2 | 0.540 | 0.460 |
| 349.6 | 0.609 | 0.391 |
| 355.3 | 0.706 | 0.294 |
| 363.8 | 0.844 | 0.156 |
| 368.7 | 0.935 | 0.065 |
| 372.5 | 1.000 | 0.000 |
Authors report eutectic point occurs at x2 = 0.460 and at T/K = 346.2.
