SDS Volume (2036)
Volume 59. Polycyclic Aromatic Hydrocarbons: Binary Non-aqueous Systems, Part II Solutes F-Z, p 23
Original Measurements
Shinomiya, C.; J. Chem. Soc. Japan 1940, 15, 259-270.
Variables:
Room Temp: Temperature $\pu{K}$
Prepared by:
Method/Apparatus/Procedure:
No experimental details given in paper.
Source and Purity of Materials:
- Purity and chemical source were not specified in paper.
- Purity and chemical source were not specified in paper.
Estimated Errors:
Ambient temperature: T/K: ±precision 0.2. (compiler). x1: ±0.002 (compiler).
Components:
- Fluoranthene, $\ce{ C16H10 }$; [206-44-0] NIST WebBook
- 1,3,5-Trinitrobenzene, $\ce{ C6H6N3O6 }$; [99-35-4] NIST WebBook
Experimental Data
| $T$ ($\pu{K}$) | $x_{1}$ | $x_{2}$ |
|---|---|---|
| 396.2 | 0.000 | 1.000 |
| 413.0 | 0.107 | 0.893 |
| 437.7 | 0.172 | 0.828 |
| 461.7 | 0.262 | 0.738 |
| 461.5 | 0.286 | 0.714 |
| 476.2 | 0.419 | 0.581 |
| 477.7 | 0.511 | 0.489 |
| 477.2 | 0.531 | 0.469 |
| 473.2 | 0.624 | 0.376 |
| 456.2 | 0.717 | 0.283 |
| 397.7 | 0.839 | 0.161 |
| 379.2 | 0.951 | 0.049 |
| 382.7 | 1.000 | 0.000 |
Authors reports formations of a 1:1 fluoranthene - 1,3,5-trinitrobenzene yellow molecular compound having a melting point temperature of 478.2 K. Two eutectic points occur at x1 = 0.040 and T/K = 376.2, and at x1 = 0.868 and T/K = 371.7.
