Naphthalene with 2-Butanone and Water (IUPAC SDS Volume 59)

SDS Volume

Volume 59. Polycyclic Aromatic Hydrocarbons: Binary Non-aqueous Systems, Part II Solutes F-Z, p None

Source Publication

Sarker, M.; Wilson, D.; J. Tennessee Acad. Sci. 1986, 61, 69-74.

Conditions:

Room Temp: Ambient Room Temperature

Compiler:

W.E. Acree, Jr.

Methodology:

Gas chromatographic equipped with flame ionization detection.
Binary mixtures were prepared by weight. Excess solute and solvent placed in closed glass bottles and allowed to equilibrate at ambient room temperature for several days. A 100 mL aliquot removed and naphthalene concentrated by hexane extraction. Concentrations determined by gas chromatography.

Sample Information:
  1. Purity and chemical source not given in paper.
  2. Purity and chemical source not given.
  3. Purity and chemical source not given.
Measurement Errors:

Ambient temperature: T/K: Unknown. x1: ±0.001 (compiler). x1: ±8% (relative error; compiler).

System Components:
  1. Naphthalene, $\ce{ C10H8 }$; [91-20-3] NIST WebBook
  2. 2-Butanone, $\ce{ C4H8O }$; [78-93-3] NIST WebBook
  3. Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook
Experimental Data

Actual experimental data not given in cited paper. Solubilities, c1/(mg L-1), expressed in terms of the equation: c1/(mg L-1) = 36.5 (1 + 3.4 × 104 x22.45). Mole fraction compositions of 2-butanone ranged between x2 = 0.01 to x2 = 0.02.

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