SDS Volume
Volume 59. Polycyclic Aromatic Hydrocarbons: Binary Non-aqueous Systems, Part II Solutes F-Z, p None
Source Publication
Kremann, R.; Monatsch. Chem. 1904, 25, 1271-1292.
Conditions:
Room Temp: Temperature $\pu{K}$
Compiler:
Methodology:
Binary mixtures prepared by weight. While the experimental details were not given in the paper, compiler speculates (based upon quantity of material used) that the sample was sealed in a glass container, temperature slowly varied, and the phase diagram determined by visually noting the temperature at which the last/first crystal of solid disappeared/appeared.
Sample Information:
- Purity and chemical source were not specified in paper.
- Purity and chemical source were not specified in paper.
Measurement Errors:
Ambient temperature: T/K: precision ±0.2 (compiler). x1: ±0.002 (compiler).
System Components:
- Naphthalene, $\ce{ C10H8 }$; [91-20-3] NIST WebBook
- 2-Nitrophenol, $\ce{ C6H5NO3 }$; [88-75-5] NIST WebBook
Experimental Data
| $T$ ($\pu{K}$) | $x_{1}$ | $x_{2}$ |
|---|---|---|
| 318.2 | 0.000 | 1.000 |
| 315.2 | 0.057 | 0.943 |
| 312.2 | 0.120 | 0.880 |
| 307.2 | 0.235 | 0.765 |
| 304.2 | 0.288 | 0.712 |
| 304.2 | 0.311 | 0.689 |
| 305.2 | 0.314 | 0.686 |
| 307.2 | 0.341 | 0.659 |
| 308.0 | 0.346 | 0.654 |
| 312.7 | 0.390 | 0.610 |
| 317.2 | 0.440 | 0.560 |
| 322.2 | 0.507 | 0.493 |
| 325.7 | 0.549 | 0.451 |
| 329.2 | 0.598 | 0.402 |
| 343.7 | 0.660 | 0.340 |
| 337.2 | 0.720 | 0.280 |
| 343.2 | 0.825 | 0.175 |
| 350.2 | 0.925 | 0.075 |
| 353.7 | 1.000 | 0.000 |
