SDS Volume (2000)

Volume 59. Polycyclic Aromatic Hydrocarbons: Binary Non-aqueous Systems, Part II Solutes F-Z, p None

Original Measurements

Kremann, R.; Monatsch. Chem. 1904, 25, 1271-1292.

Variables:

Room Temp: Temperature $\pu{K}$

Prepared by:

W.E. Acree, Jr.

Method/Apparatus/Procedure:

Binary mixtures prepared by weight. While the experimental details were not given in the paper, compiler speculates (based upon quantity of material used) that the sample was sealed in a glass container, temperature slowly varied, and the phase diagram determined by visually noting the temperature at which the last/first crystal of solid disappeared/appeared.

Source and Purity of Materials:
  1. Purity and chemical source were not specified in paper.
  2. Purity and chemical source were not specified in paper.
Estimated Errors:

Ambient temperature: T/K: precision ±0.2 (compiler). x1: ±0.002 (compiler).

Components:
  1. Naphthalene, $\ce{ C10H8 }$; [91-20-3] NIST WebBook
  2. 2-Nitrophenol, $\ce{ C6H5NO3 }$; [88-75-5] NIST WebBook
Experimental Data
$T$ ($\pu{K}$) $x_{1}$ $x_{2}$
318.2 0.0001.000
315.2 0.0570.943
312.2 0.1200.880
307.2 0.2350.765
304.2 0.2880.712
304.2 0.3110.689
305.2 0.3140.686
307.2 0.3410.659
308.0 0.3460.654
312.7 0.3900.610
317.2 0.4400.560
322.2 0.5070.493
325.7 0.5490.451
329.2 0.5980.402
343.7 0.6600.340
337.2 0.7200.280
343.2 0.8250.175
350.2 0.9250.075
353.7 1.0000.000

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