Components:
(1) Naphthalene,
C10H8; [91-20-3]
NIST WebBook
(2) 1,3,5-Trimethyl-2,4,6-trinitrobenzene,
C9H9N3O6; [602-96-0]
NIST WebBook
Original Measurements
Hammick, D. L.; Hellicar, A.; J. Chem. Soc. 1938, 761-763.
Variables:
Ambient temperature: Temperature
Prepared by:
Method/Apparatus/Procedure:
Temperatures of solid-liquid equilibrium were determined by the synthetic method. Weighed amounts of the two components were sealed in tubes, temperature slowly varied until a mean temperature was found at which a small crystal of the solid phase remained unchanged.
Source and Purity of Materials:
- Purity and chemical source were not specified in paper.
- Purity and chemical source were not specified in paper.
Estimated Errors:
Ambient temperature: T/K: precision ±0.3 (compiler). x1: ±0.005 (compiler).
Experimental Values:
| T (K) | x1 | x2 |
|---|---|---|
| 505.2 | 0.0 | 1.0 |
| 502.2 | 1.0 x 10-1 | 9.0 x 10-1 |
| 493.9 | 2.0 x 10-1 | 8.0 x 10-1 |
| 489.7 | 2.7 x 10-1 | 7.3 x 10-1 |
| 478.4 | 3.7 x 10-1 | 6.3 x 10-1 |
| 465.7 | 4.9 x 10-1 | 5.1 x 10-1 |
| 450.2 | 6.0 x 10-1 | 4.0 x 10-1 |
| 433.2 | 7.1 x 10-1 | 2.9 x 10-1 |
| 408.7 | 8.0 x 10-1 | 2.0 x 10-1 |
| 395.2 | 8.4 x 10-1 | 1.6 x 10-1 |
| 368.5 | 9.0 x 10-1 | 1.0 x 10-1 |
| 351.7 | 9.8 x 10-1 | 2 x 10-2 |
| 353.2 | 1.0 | 0.0 |
(None) Phase diagram depicted in paper shows a simple eutectic system.
