SDS Volume (1987)
Volume 59. Polycyclic Aromatic Hydrocarbons: Binary Non-aqueous Systems, Part II Solutes F-Z, p None
Original Measurements
Shinomiya, C.; Nippon Kagaku Kaishi 1939, 60, 170-182.
Variables:
Room Temp: Temperature $\pu{K}$
Prepared by:
Method/Apparatus/Procedure:
No experimental details given in paper. Compiler speculates that the transition temperatures were probably determined by visually observing the temperature corresponding to the first crystal formation (or complete liquefication).
Source and Purity of Materials:
- Purity and chemical source were not specified in paper.
- Purity and chemical source were not specified in paper.
Estimated Errors:
Ambient temperature: T/K: precision ±0.3 (compiler). x1: ±0.002 (compiler).
Components:
- Naphthalene, $\ce{ C10H8 }$; [91-20-3] NIST WebBook
- 3-Nitrobenzaldehyde, $\ce{ C7H5NO3 }$; [99-61-6] NIST WebBook
Experimental Data
| $T$ ($\pu{K}$) | $x_{1}$ | $x_{2}$ |
|---|---|---|
| 330.2 | 0.000 | 1.000 |
| 325.7 | 0.097 | 0.903 |
| 319.7 | 0.216 | 0.784 |
| 315.7 | 0.344 | 0.656 |
| 312.7 | 0.376 | 0.624 |
| 310.7 | 0.397 | 0.603 |
| 310.2 | 0.401 | 0.599 |
| 316.7 | 0.475 | 0.525 |
| 321.7 | 0.531 | 0.469 |
| 322.7 | 0.549 | 0.451 |
| 330.7 | 0.642 | 0.358 |
| 332.2 | 0.644 | 0.356 |
| 345.2 | 0.837 | 0.173 |
| 353.2 | 1.000 | 0.000 |
