SDS Volume (1967)

Volume 59. Polycyclic Aromatic Hydrocarbons: Binary Non-aqueous Systems, Part II Solutes F-Z, p None

Original Measurements

Domanska, U.; Pol. J. Chem. 1981, 55, 1715-1720.

Variables:

Room Temp: Temperature $\pu{K}$

Prepared by:

W.E. Acree, Jr.

Method/Apparatus/Procedure:

Constant temperature bath and a precision thermometer.
Solubilities were measured using a dynamic method. Mixtures of known concentrations were sealed in thick-walled glass ampoules and placed in a constant temperature to equilibrate. Bath temperature was slowly increased by 2 K per hour. Solubility determined by visually noting the temperature at which the last trace of solid solute disappeared.

Source and Purity of Materials:
  1. Purity not specified, P.O.Ch., Gliwice, Poland, was vacuum sublimed to a melting temperature of 80.25°C.
  2. Initial purity not specified, KochLight, was used as received.
Estimated Errors:

Ambient temperature: T/K: precision ±0.1. x1: to 3 significant figs. (compiler).

Components:
  1. Naphthalene, $\ce{ C10H8 }$; [91-20-3] NIST WebBook
  2. 1-Octanol, $\ce{ C8H18O }$; [111-87-5] NIST WebBook
Experimental Data
$T$ ($\pu{K}$) $x_{1}$ $x_{2}$
280.95 0.0690.931
284.35 0.0770.923
286.75 0.0840.916
289.95 0.0920.908
291.95 0.0990.901
294.15 0.1080.892
295.55 0.1160.884
298.55 0.1240.976
302.35 0.1390.861
305.15 0.1530.847
308.25 0.1690.831
311.95 0.1940.806
315.45 0.2210.779
317.45 0.2400.760
320.65 0.2670.733
323.35 0.2990.701
325.95 0.3280.672
331.55 0.4220.578

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