SDS Volume (195)

Volume 20. Halogenated Benzenes, Toluenes and Phenols with Water, p 85

Original Measurements

Chiou, C. T.; Freed, V. H.; "Chemodynamic Studies on Bench Mark Industrial Chemicals"; NTIS: Springfield, VA, 1977; PB-274263.

Variables:

Room Temp: 3 - 34 °C

Prepared by:

A.L. Horvath

Method/Apparatus/Procedure:

An excess of 1,2-dichlorobenzene, 5-10 g, was equilibrated with 100 mL distilled water in a bottle for 24 hours at constant temperature. The saturated aqueous phase was removed from the container and analyzed by gas chromatography using a chromatograph equipped with $\ce{^{63}Ni}$ EC detector. The GLC column was packed with porous polymer Chromosorb 101. Further details on the determinations and evaluations of experimental procedures have been included in [1].

Source and Purity of Materials:
  1. Commercial reagent, used as received.
  2. Distilled.
Estimated Errors:

Ambient temperature: ±0.5 K.
Mass concentration (m/v) (1): ±10% (compiler).

References

1 Chiou, C. T.; Schmedding, D. W.; Test. Protoc. Environ. Fate Mov. Toxicants, Proc. Symp., 1980, pp 28-42.

Components:
  1. 1,2-Dichlorobenzene, $\ce{ C6H4Cl2 }$; [95-50-1] NIST WebBook
  2. Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook
Experimental Data
$T$ (°C) $x_{1}$ $C_{1}$ (mol/dm3)
3 1.630 x 10-59.046 x 10-4
20 1.817 x 10-51.007 x 10-3
34 1.997 x 10-51.102 x 10-3

(a) Reported.

(b) Calculated by F. W. Getzen.

(c) Calculated by the compiler.

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