SDS Volume

Volume 59. Polycyclic Aromatic Hydrocarbons: Binary Non-aqueous Systems, Part II Solutes F-Z, p None

Source Publication

Speyers, C. L.; Am. J. Sci. 1902, 14, 293-302.

Conditions:

Room Temp: Temperature $\pu{K}$

Compiler:

W.E. Acree, Jr.

Methodology:

Experimental procedure only marginally described by author. Excess solute and solvent were equilibrated in a constant temperature water bath for between 10-30 minutes. Saturated solution was withdrawn through a coarse filter and analyzed by specific gravity. Author noted that evaporation to dryness and weighing the residue was subject to too much decomposition.

Sample Information:
  1. Purity not given, Kahlbaum, was recrystallized from alcohol to a melting point temperature of 80.1°C.
  2. Marked absolute, from Eimer and Amend and Chas. Cooper and Co., dried over calcium oxide and distilled before use.
Measurement Errors:

Ambient temperature: T/K: precision ±0.1. x1: ±8% (relative error, compiler).

System Components:
  1. Naphthalene, $\ce{ C10H8 }$; [91-20-3] NIST WebBook
  2. Ethanol, $\ce{ C2H6O }$; [64-17-5] NIST WebBook
Experimental Data
$T$ ($\pu{K}$) $x_{1}$ $x_{2}$
273.2 0.01800.9820
281.8 0.02130.9787
305.0 0.04820.9518
320.1 0.09700.9030
343.0 0.64230.3577

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