Compilation - Naphthalene with Chrysene (IUPAC SDS Volume 59)
SDS Volume (1892)
Volume 59. Polycyclic Aromatic Hydrocarbons: Binary Non-aqueous Systems, Part II Solutes F-Z, p None
Original Measurements
Kravchenko, V. M.; Pastukhova, I. S.; Proc. Acad. Sci. USSR; Sect. Chem. 1956, 111, 667-669.
Variables:
Room Temp: Temperature $\pu{K}$
Prepared by:
Method/Apparatus/Procedure:
Phase diagram was determined using a thermal analysis method [1], supplemented by visual observation.
Source and Purity of Materials:
- Purity and chemical source were not specified in paper, was recrystallized before use.
- Purity and chemical source were not specified in paper, was recrystallized before use.
Estimated Errors:
Ambient temperature: T/K: precision ±0.2 (compiler). x1: ±0.002 (compiler).
References
1 Kravchenko, V. M.; Zh. Fiz. Khim. 1939, 13, 133-145.
Components:
- Naphthalene, $\ce{ C10H8 }$; [91-20-3] NIST WebBook
- Chrysene, $\ce{ C18H12 }$; [218-01-9] NIST WebBook
Experimental Data
| $T$ ($\pu{K}$) | $x_{1}$ | $x_{2}$ |
|---|---|---|
| 528.2 | 0.000 | 1.000 |
| 520.2 | 0.097 | 0.903 |
| 511.4 | 0.183 | 0.817 |
| 500.2 | 0.298 | 0.702 |
| 487.5 | 0.407 | 0.593 |
| 476.2 | 0.496 | 0.504 |
| 459.7 | 0.593 | 0.407 |
| 442.4 | 0.710 | 0.290 |
| 417.8 | 0.798 | 0.202 |
| 406.2 | 0.843 | 0.157 |
| 388.4 | 0.897 | 0.103 |
| 351.0 | 0.958 | 0.042 |
| 351.7 | 0.975 | 0.025 |
| 353.2 | 1.000 | 0.000 |
