Compilation - Anthracene with Benzene (IUPAC SDS Volume 58)
SDS Volume (1792)
Volume 58. Polycyclic Aromatic Hydrocarbons: Binary Non-aqueous Systems, Part I Solutes A-E, p 41
Original Measurements
McLaughlin, E.; Zainal, H. A.; J. Chem. Soc. 1959, 863-867.
Variables:
Room Temp: 309.0 - 343.4 $\pu{K}$
Prepared by:
Method/Apparatus/Procedure:
Constant temperature bath and a precision thermometer. Mixtures of known concentrations sealed in glass ampoules and placed in constant temperature to equilibrate. Samples were rotated while bath temperature slowly increased. Solubility determined by noting the temperature at which the last trace of solid solute disappeared.
Source and Purity of Materials:
- Purity, source and purification procedure not specified.
- “AnalaR”, was dried over sodium wire and freshly distilled before use.
Estimated Errors:
Ambient temperature: T/K: precision ±0.1.
Mole fraction - Liquid (1): x1: ±0.0003 (compiler).
Components:
- Anthracene, $\ce{ C14H10 }$; [120-12-7] NIST WebBook
- Benzene, $\ce{ C6H6 }$; [71-43-2] NIST WebBook
Experimental Data
| $T$ ($\pu{K}$) | $x_{1}$ | $x_{2}$ |
|---|---|---|
| 309.0 | 0.0103 | 0.9897 |
| 315.6 | 0.0130 | 0.9870 |
| 323.8 | 0.0173 | 0.9827 |
| 332.8 | 0.0225 | 0.9775 |
| 343.4 | 0.0315 | 0.9685 |
