Compilation - Chrysene with Fluorene (IUPAC SDS Volume 58)
SDS Volume (1747)
Volume 58. Polycyclic Aromatic Hydrocarbons: Binary Non-aqueous Systems, Part I Solutes A-E, p 293
Original Measurements
Kravchenko, V. M.; Pastukhova, I. S.; Proc. Acad. Sci. USSR; Sect. Chem. 1956, 111, 667-669.
Variables:
Room Temp: 381.2 - 528.2 $\pu{K}$
Prepared by:
Method/Apparatus/Procedure:
Phase diagram was determined using a thermal analysis method [1], supplemented by visual observation.
Source and Purity of Materials:
- Purity and chemical source were not specified in paper, was recrystallized before use.
- Purity and chemical source were not specified in paper, was recrystallized before use.
Estimated Errors:
Ambient temperature: T/K: precision ±0.2 (Compiler).
Mole fraction - Liquid (1): x1: ±0.002 (Compiler).
References
1 Kravchenko, V. M.; Zh. Fiz. Khim. 1939, 13, 133-145.
Components:
- Chrysene, $\ce{ C18H12 }$; [218-01-9] NIST WebBook
- Fluorene, $\ce{ C13H10 }$; [86-73-7] NIST WebBook
Experimental Data
| $T$ ($\pu{K}$) | $x_{1}$ | $x_{2}$ |
|---|---|---|
| 387.2 | 0.000 | 1.000 |
| 384.4 | 0.052 | 0.948 |
| 381.2 | 0.098 | 0.902 |
| 395.7 | 0.129 | 0.871 |
| 419.5 | 0.205 | 0.795 |
| 445.4 | 0.320 | 0.680 |
| 458.7 | 0.403 | 0.597 |
| 480.2 | 0.555 | 0.445 |
| 491.6 | 0.650 | 0.350 |
| 504.2 | 0.754 | 0.246 |
| 513.9 | 0.861 | 0.139 |
| 528.2 | 1.000 | 0.000 |
