SDS Volume
Volume 58. Polycyclic Aromatic Hydrocarbons: Binary Non-aqueous Systems, Part I Solutes A-E, p 292
Source Publication
Kravchenko, V. M.; Pastukhova, I. S.; Proc. Acad. Sci. USSR; Sect. Chem. 1956, 111, 667-669.
Conditions:
Room Temp: 364.2 - 528.2 $\pu{K}$
Compiler:
Methodology:
Phase diagram was determined using a thermal analysis method [1], supplemented by visual observation.
Sample Information:
- Purity and chemical source were not specified in paper, was recrystallized before use.
- Purity and chemical source were not specified in paper, was recrystallized before use.
Measurement Errors:
Ambient temperature: T/K: precision ±0.2 (Compiler).
Mole fraction - Liquid (1): x1: ±0.002 (Compiler).
Methodology Citation
1 Kravchenko, V. M.; Zh. Fiz. Khim. 1939, 13, 133-145.
System Components:
- Chrysene, $\ce{ C18H12 }$; [218-01-9] NIST WebBook
- Acenaphthene, $\ce{ C12H10 }$; [83-32-9] NIST WebBook
Experimental Data
| $T$ ($\pu{K}$) | $x_{1}$ | $x_{2}$ |
|---|---|---|
| 368.2 | 0.000 | 1.000 |
| 366.4 | 0.034 | 0.966 |
| 364.2 | 0.072 | 0.928 |
| 378.5 | 0.101 | 0.899 |
| 416.2 | 0.204 | 0.796 |
| 437.4 | 0.296 | 0.704 |
| 457.0 | 0.404 | 0.596 |
| 471.5 | 0.501 | 0.499 |
| 477.8 | 0.613 | 0.387 |
| 500.2 | 0.722 | 0.278 |
| 513.2 | 0.853 | 0.147 |
| 528.2 | 1.000 | 0.000 |
