SDS Volume (168)

Volume 20. Halogenated Benzenes, Toluenes and Phenols with Water, p 56

Original Measurements

Yalkowsky, S. H.; Orr, R. J.; Valvani, S. C.; Ind. Eng. Chem. Fundam. 1979, 18(4), 351-3.

Variables:

Room Temp: 25 °C

Prepared by:

A. Vesala

Method/Apparatus/Procedure:

A small excess of solute in water was agitated for a period of 4-48 hours (the exact time for equilibration was not reported in single cases) and then filtered. The saturated solution was extracted with a small volume of methylene chloride which was then assayed spectrophotometrically. At least two independent determinations were carried out.

Source and Purity of Materials:
  1. Commercial reagent (Aldrich or Eastman), used as received.
  2. Source and purity not specified.
Estimated Errors:

Ambient temperature: ±1 K (authors).
Mass concentration (m/v) (1): ±10% (authors).

Components:
  1. 1-Bromo-4-iodobenzene, $\ce{ C6H4BrI }$; [589-87-7] NIST WebBook
  2. Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook
Experimental Data
$T$ (°C) $x_{1}$ $C_{1}$ (mol/dm3)
25 5.06 x 10-72.8 x 10-5

(a) Calculated by F. W. Getzen.

(b) Reported.

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