Compilation - Pentachlorobenzene with Water (IUPAC SDS Volume 20)
SDS Volume (155)
Volume 20. Halogenated Benzenes, Toluenes and Phenols with Water, p 4
Original Measurements
Yalkowsky, S. H.; Orr, R. J.; Valvani, S. C.; Ind. Eng. Chem. Fundam. 1979, 18(4), 351-3.
Variables:
Room Temp: 25 °C
Prepared by:
Method/Apparatus/Procedure:
A small excess of solute in water was agitated for a period of 4-48 hours (the exact time for equilibration was not reported in single cases) and then filtered. The saturated solution was extracted with a small volume of methylene chloride which was then assayed spectrophotometrically. At least two independent determinations were carried out.
Source and Purity of Materials:
- Commercial reagent (Aldrich or Eastman), Used as received.
- Source and purity not specified.
Estimated Errors:
Ambient temperature: ±1 K (authors).
Mass concentration (m/v) (1): ±10% (authors).
Components:
- Pentachlorobenzene, $\ce{ C6HCl5 }$; [608-93-5] NIST WebBook
- Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook
Experimental Data
| $T$ (°C) | $C_{1}$ (mol/dm3) | Cm1 (g(1)/dm3) | $x_{1}$ |
|---|---|---|---|
| 25 | 2.2 x 10-6 | 5.51 x 10-4 | 3.95 x 10-8 |
(a) Calculated by F. W. Getzen.
(b) Reported.
