SDS Volume

Volume 58. Polycyclic Aromatic Hydrocarbons: Binary Non-aqueous Systems, Part I Solutes A-E, p 174

Source Publication

Choi, P. B.; Williams, C. P.; Buehring, K. G.; McLaughlin, E.; J. Chem. Eng. Data 1985, 30, 403-409.

Conditions:

Room Temp: 307.95 - 333.15 $\pu{K}$

Compiler:

W.E. Acree, Jr.

Methodology:

Constant temperature bath and a precision thermometer. Mixtures of known concentrations sealed in glass ampoules and placed in constant temperature to equilibrate. Samples were rotated while bath temperature slowly increased. Solubility determined by visual noting the temperature at which the last trace of solid solute appeared.

Sample Information:
  1. 99.6%, Eastman Kodak Chemical Company, Rochester, New York, USA, was passed over activated alumina and recrystallized from toluene.
  2. Gold Label, 99.9%, Aldrich Chemical Company, was used as received.
Measurement Errors:

Ambient temperature: T/K: precision ±0.1.
Mole fraction - Liquid (1): x1: ±0.0003.

System Components:
  1. Biphenyl, $\ce{ C12H10 }$; [92-52-4] NIST WebBook
  2. Benzene, $\ce{ C6H6 }$; [71-43-2] NIST WebBook
Experimental Data
$T$ ($\pu{K}$) $x_{1}$ $x_{2}$
307.95 0.48330.5167
313.85 0.55610.4439
316.85 0.59320.4068
323.65 0.68970.3103
328.95 0.77110.2289
333.15 0.84220.1578

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