Compilation - Acenaphthene with Methanol (IUPAC SDS Volume 58)
SDS Volume (1508)
Volume 58. Polycyclic Aromatic Hydrocarbons: Binary Non-aqueous Systems, Part I Solutes A-E, p 18
Original Measurements
Speyers, C. L.; Am. J. Sci. 1902, 14, 293-302.
Variables:
Room Temp: 273.2 - 335.5 $\pu{K}$
Prepared by:
Method/Apparatus/Procedure:
Experimental procedure only marginally described by author. Excess solute and solvent were equilibrated in a constant temperature water bath for between 10-30 minutes. Saturated solution was withdrawn through a coarse filter and analyzed by specific gravity. Author noted that evaporation to dryness and weighing the residue was subject to too much decomposition.
Source and Purity of Materials:
- Purity not given, Kahlbaum, was recrystallized from alcohol to a melting point temperature of 93.5°C.
- Marked “Acetonfrei”, from Kahlbaum dried over calcium oxide and distilled before use.
Estimated Errors:
Ambient temperature: T/K: precision ±0.1.
Mass concentration (m/v) (1): x1: ±8% (relative error, compiler).
Components:
- Acenaphthene, $\ce{ C12H10 }$; [83-32-9] NIST WebBook
- Methanol, $\ce{ CH4O }$; [67-56-1] NIST WebBook
Experimental Data
| $T$ ($\pu{K}$) | $x_{1}$ | $x_{2}$ |
|---|---|---|
| 273.2 | 3.9 x 10-3 | 0.9961 |
| 285.6 | 3.8 x 10-3 | 0.9962 |
| 303.9 | 7.3 x 10-3 | 0.9927 |
| 319.2 | 0.0155 | 0.9845 |
| 335.5 | 0.0246 | 0.9754 |
