Compilation - Acenaphthene with Chrysene (IUPAC SDS Volume 58)
SDS Volume (1463)
Volume 58. Polycyclic Aromatic Hydrocarbons: Binary Non-aqueous Systems, Part I Solutes A-E, p 15
Original Measurements
Kravchenko, V. M.; Pastukhova, I. S.; Proc. Acad. Sci. USSR; Sect. Chem. 1956, 111, 667-669.
Variables:
Room Temp: 368.2 - 528.2 $\pu{K}$
Prepared by:
Method/Apparatus/Procedure:
Phase diagram was determined using a thermal analysis method [1], supplemented by visual observation.
Source and Purity of Materials:
- Purity and chemical source were not specified in paper, was recrystallized before use.
- Purity and chemical source were not specified in paper, was recrystallized before use.
Estimated Errors:
Ambient temperature: T/K: precision ±0.2 (Compiler).
Mole fraction - Liquid (1): x1: ±0.002 (Compiler).
References
1 Kravchenko, V. M.; Zh. Fiz. Khim. 1939, 13, 133-145.
Components:
- Acenaphthene, $\ce{ C12H10 }$; [83-32-9] NIST WebBook
- Chrysene, $\ce{ C18H12 }$; [218-01-9] NIST WebBook
Experimental Data
| $T$ ($\pu{K}$) | $x_{1}$ | $x_{2}$ |
|---|---|---|
| 528.2 | 0.000 | 1.000 |
| 513.2 | 0.147 | 0.853 |
| 500.2 | 0.278 | 0.722 |
| 477.8 | 0.387 | 0.613 |
| 471.5 | 0.499 | 0.501 |
| 457.0 | 0.596 | 0.404 |
| 437.4 | 0.704 | 0.296 |
| 416.2 | 0.796 | 0.204 |
| 378.5 | 0.899 | 0.101 |
| 364.2 | 0.928 | 0.072 |
| 366.4 | 0.966 | 0.034 |
| 368.2 | 1.000 | 0.000 |
