Compilation - Acenaphthene with Phenanthrene (IUPAC SDS Volume 58)
SDS Volume (1441)
Volume 58. Polycyclic Aromatic Hydrocarbons: Binary Non-aqueous Systems, Part I Solutes A-E, p 13
Original Measurements
Kravchenko, V. M.; Pastukhova, I. S.; Zh. Fiz. Khim. 1957, 31, 1802-1811.
Variables:
Room Temp: 368.3 - 372.5 $\pu{K}$
Prepared by:
Method/Apparatus/Procedure:
Phase diagram was determined using a thermal analysis method [1], supplemented by visual observation.
Source and Purity of Materials:
- Purity and chemical source were not specified in paper, was recrystallized before use.
- Purity and chemical source were not specified in paper, was recrystallized before use.
Estimated Errors:
Ambient temperature: T/K: precision ±0.2 (Compiler).
Mole fraction - Liquid (1): x1: ±0.002 (Compiler).
References
1 Kravchenko, V. M.; Zh. Fiz. Khim. 1939, 13, 133-145.
Components:
- Acenaphthene, $\ce{ C12H10 }$; [83-32-9] NIST WebBook
- Phenanthrene, $\ce{ C14H10 }$; [85-01-8] NIST WebBook
Experimental Data
| $T$ ($\pu{K}$) | $x_{1}$ | $x_{2}$ |
|---|---|---|
| 372.5 | 0.000 | 1.000 |
| 357.4 | 0.199 | 0.801 |
| 347.7 | 0.293 | 0.707 |
| 338.7 | 0.386 | 0.614 |
| 329.0 | 0.492 | 0.508 |
| 334.5 | 0.541 | 0.459 |
| 339.1 | 0.599 | 0.401 |
| 346.7 | 0.686 | 0.314 |
| 355.0 | 0.796 | 0.204 |
| 362.0 | 0.901 | 0.099 |
| 368.3 | 1.000 | 0.000 |
