SDS Volume
Volume 58. Polycyclic Aromatic Hydrocarbons: Binary Non-aqueous Systems, Part I Solutes A-E, p 82
Source Publication
Shinomiya, C.; J. Chem. Soc. Japan 1940, 15, 259-270.
Conditions:
Room Temp: 399.2 - 490.2 $\pu{K}$
Compiler:
Methodology:
No experimental details given in paper.
Sample Information:
- Purity and chemical source not specified in paper.
- Purity and chemical source not specified in paper.
Measurement Errors:
Ambient temperature: T/K: precision ±0.2 (Compiler).
Mole fraction - Liquid (1): x1: ±0.002 (Compiler).
System Components:
- Anthracene, $\ce{ C14H10 }$; [120-12-7] NIST WebBook
- 1,2,3,5-Tetranitrobenzene, $\ce{ C6H2N4O8 }$; [3698-53-1] NIST WebBook
Experimental Data
| $T$ ($\pu{K}$) | $x_{1}$ | $x_{2}$ |
|---|---|---|
| 399.2 | 0.000 | 1.000 |
| 398.2 | 0.065 | 0.935 |
| 418.2 | 0.158 | 0.842 |
| 436.2 | 0.307 | 0.693 |
| 442.2 | 0.396 | 0.604 |
| 444.2 | 0.513 | 0.487 |
| 441.7 | 0.570 | 0.430 |
| 449.2 | 0.646 | 0.354 |
| 459.2 | 0.699 | 0.301 |
| 462.2 | 0.729 | 0.271 |
| 490.2 | 1.000 | 0.000 |
Author reports formation of a 1:1 anthracene - 1,2,3,5-tetranitrobenzene molecular compound having a melting point temperature of 444.2 K. Two eutectic points occur at x1 = 0.055 and T/K = 393.7, and at x1 = 0.605 and T/K = 436.2.
