SDS Volume

Volume 57. Ethene, p 124

Source Publication

Chou, J. S.; Chao, K. C.; J. Chem. Eng. Data 1989, 34, 68-70.

Conditions:

Room Temp: 373.25 - 573.25 $\pu{K}$
Pressure: 1.02 - 5.06 $\pu{MPa}$

Compiler:

W. Hayduk

Methodology:

Ethene is bubbled through a presaturator and then through the equilibrium cell, both being filled with the molten solvent. The cell is thermostated in a nitrogen bath. After saturation, a (molten) liquid sample is withdrawn into an evacuated trap connected to a gas handling system. The solvent solidifies, and the volume of the gas released is measured in a burette over water at a known temperature and pressure. The mass of the solid solvent is determined. Further details are in [1].

Sample Information:
  1. Ethene was from Matheson Gas Products at a specified purity of 99.5%.
  2. Hexatriacontane was from the Aldrich Chemical Company at a specified purity of 99.0%.
Measurement Errors:

Ambient temperature: δT/K = ±0.1
Mass concentration (m/v) (1): δx/x = ±0.02 (compiler)
Pressure: δP/atm = ±0.05

Methodology Citation

1 Huang, S. H.; Lin, H. M.; Chao, K. C., Fluid Phase Equil. 1987, 36, 141.

System Components:
  1. Ethene, $\ce{ C2H4 }$; [74-85-1] NIST WebBook
  2. Hexatriacontane, $\ce{ C36H74 }$; [630-06-8] NIST WebBook
Experimental Data
$T$ ($\pu{K}$) $T$ (°C) $x_{1}$ $P$ ($\pu{MPa}$)
373.25100.1 0.017020.10131
373.25100.1 0.1721.0261
373.25100.1 0.2922.0261
373.25100.1 0.3933.0371
373.25100.1 0.4674.0501
373.25100.1 0.5275.0591
473.05199.9 0.011220.10131
473.05199.9 0.1131.0221
473.05199.9 0.2052.0331
473.05199.9 0.2802.9641
473.05199.9 0.3524.0541
473.05199.9 0.4035.0631
573.05299.9 9.3 x 10-320.10131
573.05299.9 0.09371.0231
573.05299.9 0.1772.0341
573.05299.9 0.2423.0391
573.05299.9 0.3064.0501
573.05299.9 0.3615.0671

(1) Calculated by the compiler.

(2) Estimated by compiler

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