SDS Volume
Volume 57. Ethene, p 124
Source Publication
Chou, J. S.; Chao, K. C.; J. Chem. Eng. Data 1989, 34, 68-70.
Conditions:
Room Temp:
373.25 - 573.25
$\pu{K}$
Pressure:
1.02 - 5.06
$\pu{MPa}$
Compiler:
Methodology:
Ethene is bubbled through a presaturator and then through the equilibrium cell, both being filled with the molten solvent. The cell is thermostated in a nitrogen bath. After saturation, a (molten) liquid sample is withdrawn into an evacuated trap connected to a gas handling system. The solvent solidifies, and the volume of the gas released is measured in a burette over water at a known temperature and pressure. The mass of the solid solvent is determined. Further details are in [1].
Sample Information:
- Ethene was from Matheson Gas Products at a specified purity of 99.5%.
- Hexatriacontane was from the Aldrich Chemical Company at a specified purity of 99.0%.
Measurement Errors:
Ambient temperature: δT/K = ±0.1
Mass concentration (m/v) (1): δx/x = ±0.02 (compiler)
Pressure: δP/atm = ±0.05
Methodology Citation
1 Huang, S. H.; Lin, H. M.; Chao, K. C., Fluid Phase Equil. 1987, 36, 141.
System Components:
- Ethene, $\ce{ C2H4 }$; [74-85-1] NIST WebBook
- Hexatriacontane, $\ce{ C36H74 }$; [630-06-8] NIST WebBook
Experimental Data
| $T$ ($\pu{K}$) | $T$ (°C) | $x_{1}$ | $P$ ($\pu{MPa}$) |
|---|---|---|---|
| 373.25 | 100.1 | 0.01702 | 0.10131 |
| 373.25 | 100.1 | 0.172 | 1.0261 |
| 373.25 | 100.1 | 0.292 | 2.0261 |
| 373.25 | 100.1 | 0.393 | 3.0371 |
| 373.25 | 100.1 | 0.467 | 4.0501 |
| 373.25 | 100.1 | 0.527 | 5.0591 |
| 473.05 | 199.9 | 0.01122 | 0.10131 |
| 473.05 | 199.9 | 0.113 | 1.0221 |
| 473.05 | 199.9 | 0.205 | 2.0331 |
| 473.05 | 199.9 | 0.280 | 2.9641 |
| 473.05 | 199.9 | 0.352 | 4.0541 |
| 473.05 | 199.9 | 0.403 | 5.0631 |
| 573.05 | 299.9 | 9.3 x 10-32 | 0.10131 |
| 573.05 | 299.9 | 0.0937 | 1.0231 |
| 573.05 | 299.9 | 0.177 | 2.0341 |
| 573.05 | 299.9 | 0.242 | 3.0391 |
| 573.05 | 299.9 | 0.306 | 4.0501 |
| 573.05 | 299.9 | 0.361 | 5.0671 |
(1) Calculated by the compiler.
(2) Estimated by compiler


