Compilation - Ethene with Amidosulfurous acid, diethyl-, methyl ester, (N-N diethyl sulfonamide, methylester) (IUPAC SDS Volume 57)
SDS Volume (1276)
Volume 57. Ethene, p None
Original Measurements
Makitra, R. G.; Moin, F. B.; Politanskaya, T. I.; Yas'kovyak, A.; Zh. Fiz. Khim. 1975, 49, 2723-2724.
Variables:
Room Temp:
253.15 - 338.15
$\pu{K}$
Pressure:
13.3 - 96.7
$\pu{kPa}$
Prepared by:
Method/Apparatus/Procedure:
The method of measurement was not specified. It is stated in the paper that Henry's law is obeyed. A check of the data shows that Henry's law is only very approximately obeyed. Henry's constants, $H$ in mm Hg/mole fraction, as determined by the authors and as calculated by the compiler are as follows:
(authors)(compiler)
t/°C 10-2 H; 10-2H
-20 3920 2927
0 4025 3714
20 5830 6000
35 6380 6222
50 7090 7407
65 9350 13,333
Source and Purity of Materials:
- Ethene purity by gas chromatography was 99.5%.
- The solvent was washed and boiling temperature was measured at 4 mm mercury pressure as 115°C. Actual purity not determined.
Estimated Errors:
Mass concentration (m/v) (1): δx1/x1 = ±0.1 or 10% (Compiler)
Components:
- Ethene, $\ce{ C2H4 }$; [74-85-1] NIST WebBook
- N-N diethyl sulfonamide, methyl ester, $\ce{ C5H13NO2S }$; [21954-69-8] NIST WebBook
Experimental Data
The solubility is expressed as 104 x1 where x1 is the mole fraction.
| $T$ ($\pu{K}$) | $T$ (°C) | $x_{1}$ | $P$ (mm Hg) |
|---|---|---|---|
| 253.15 | -20 | 5 x 10-4 | 1E+2 |
| 253.15 | -20 | 7 x 10-4 | 2E+2 |
| 253.15 | -20 | 1 x 10-3 | 3E+2 |
| 253.15 | -20 | 1.2 x 10-3 | 4E+2 |
| 253.15 | -20 | 1.5 x 10-3 | 5E+2 |
| 253.15 | -20 | 2 x 10-3 | 6E+2 |
| 253.15 | -20 | 2.5 x 10-3 | 725 |
| 253.15 | -20 | 1.94 x 10-3 | 7.6E+2 |
| 253.15 | -20 | 2.597 x 10-3 | 7.6E+2 |
| 273.15 | 0 | 4 x 10-4 | 1E+2 |
| 273.15 | 0 | 6 x 10-4 | 2E+2 |
| 273.15 | 0 | 8 x 10-4 | 3E+2 |
| 273.15 | 0 | 1.1 x 10-3 | 4E+2 |
| 273.15 | 0 | 1.3 x 10-3 | 5E+2 |
| 273.15 | 0 | 1.7 x 10-3 | 6E+2 |
| 273.15 | 0 | 1.9 x 10-3 | 725 |
| 273.15 | 0 | 1.89 x 10-3 | 7.6E+2 |
| 273.15 | 0 | 2.05 x 10-3 | 7.6E+2 |
| 293.15 | 20 | 2 x 10-4 | 1E+2 |
| 293.15 | 20 | 5 x 10-4 | 2E+2 |
| 293.15 | 20 | 6 x 10-4 | 3E+2 |
| 293.15 | 20 | 7 x 10-4 | 4E+2 |
| 293.15 | 20 | 8 x 10-4 | 5E+2 |
| 293.15 | 20 | 1 x 10-3 | 6E+2 |
| 293.15 | 20 | 1.2 x 10-3 | 725 |
| 293.15 | 20 | 1.30 x 10-3 | 7.6E+2 |
| 293.15 | 20 | 1.27 x 10-3 | 7.6E+2 |
| 308.15 | 35 | 2 x 10-4 | 1E+2 |
| 308.15 | 35 | 4 x 10-4 | 2E+2 |
| 308.15 | 35 | 6 x 10-4 | 3E+2 |
| 308.15 | 35 | 7 x 10-4 | 4E+2 |
| 308.15 | 35 | 8 x 10-4 | 5E+2 |
| 308.15 | 35 | 8 x 10-4 | 6E+2 |
| 308.15 | 35 | 1.1 x 10-3 | 725 |
| 308.15 | 35 | 1.19 x 10-3 | 7.6E+2 |
| 308.15 | 35 | 1.22 x 10-3 | 7.6E+2 |
| 323.15 | 50 | 1 x 10-4 | 1E+2 |
| 323.15 | 50 | 3 x 10-4 | 2E+2 |
| 323.15 | 50 | 5 x 10-4 | 3E+2 |
| 323.15 | 50 | 6 x 10-4 | 4E+2 |
| 323.15 | 50 | 7 x 10-4 | 5E+2 |
| 323.15 | 50 | 8 x 10-4 | 6E+2 |
| 323.15 | 50 | 1 x 10-3 | 725 |
| 323.15 | 50 | 1.07 x 10-3 | 7.6E+2 |
| 323.15 | 50 | 1.03 x 10-3 | 7.6E+2 |
| 338.15 | 65 | - | 1E+2 |
| 338.15 | 65 | 1 x 10-4 | 2E+2 |
| 338.15 | 65 | 2 x 10-4 | 3E+2 |
| 338.15 | 65 | 3 x 10-4 | 4E+2 |
| 338.15 | 65 | 4 x 10-4 | 5E+2 |
| 338.15 | 65 | 6 x 10-4 | 6E+2 |
| 338.15 | 65 | 7 x 10-4 | 725 |
| 338.15 | 65 | 8.1 x 10-4 | 7.6E+2 |
| 338.15 | 65 | 5.7 x 10-4 | 7.6E+2 |
(1) The solubility at 101.3 kPa was calculated by the compiler from Henry's constants given in the paper.
(2) Solubility at 101.3 kPa as calculated by the compiler from H values listed below. The data were obtained from the paper deposited in VINITI, Moscow.
