SDS Volume
Volume 57. Ethene, p 300
Source Publication
Shenderei, E. R.; Zel'venskii, Ya. D.; Ivanovskii, F. P.; Russian J. Phys. Chem. 1962, 36, 415-419.
Conditions:
Room Temp:
228.05 - 248.15
$\pu{K}$
Pressure:
0.101 - 1.82
$\pu{MPa}$
Compiler:
Methodology:
Glass equilibrium cell fitted with a magnetic stirrer. Pressure measured with a Bourdon gauge. Samples of liquid analyzed by stripping out ethene. Details in [1].
Sample Information:
- Prepared from ethanol by dehydration and purified by absorption in cuprous chloride under pressure.
- Distilled.
Measurement Errors:
Ambient temperature: δT/K = ±0.1 (estimated by the compiler)
Mass concentration (m/v) (1): δxC2H4 = ±2% (estimated by compiler)
Pressure: δp/bar = ±0.3 (estimated by compiler)
Methodology Citation
1 Shenderei, E. R.; Zel'venskii, Ya. D.; Ivanovskii, F. P.; Khim. Prom. 1960, 5, 370.
System Components:
- Ethene, $\ce{ C2H4 }$; [74-85-1] NIST WebBook
- Acetone, $\ce{ C3H6O }$; [67-64-1] NIST WebBook
Experimental Data
| $T$ ($\pu{K}$) | $x_{1}$ | $P$ ($\pu{bar}$) | S ($\pu{cm3/g}$) |
|---|---|---|---|
| 248.15 | 0.0255 | 1.0 | 10.02a |
| 248.15 | 0.0750 | 3.0 | 30.98a |
| 248.15 | 0.1300 | 5.1 | 57.09a |
| 248.15 | 0.2825 | 10.1 | 150.55a |
| 248.15 | 0.3500 | 12.2 | 205.75a |
| 248.15 | 0.4680 | 15.2 | 336.13a |
| 248.15 | 0.6100 | 18.2 | 597.65a |
| 238.15 | 0.0320 | 1.0 | 12.61a |
| 238.15 | 0.1000 | 3.0 | 42.46a |
| 238.15 | 0.1650 | 5.1 | 75.51a |
| 238.15 | 0.3825 | 10.1 | 236.88a |
| 238.15 | 0.5125 | 12.2 | 402.11a |
| 238.15 | 0.8100 | 15.2 | 1.6280 x 103a |
| 228.05 | 0.0410 | 1.0 | 16.35a |
| 228.05 | 0.1275 | 3.0 | 55.87a |
| 228.05 | 0.2230 | 5.0 | 109.66a |
| 228.05 | 0.6050 | 10.1 | 515.50a |
(a) at P = 101.325 kPa.
