NIST-IUPAC Solubility Data Series

Compilation - Ethene with 2-Propanone (acetone) (IUPAC SDS Volume 57)

SDS Volume (1252)

Volume 57. Ethene, p None

Original Measurements

Voronkov, A. P.; Mislavskaya, V. S.; Mushii, R. Ya.; Drygina, V. V.; Zh. Prikl. Khim. 1979, 52, 2642.

Variables:

Room Temp: 263.15 - 373.15 $\pu{K}$
Pressure: 0.101 - 7.60 $\pu{MPa}$

Prepared by:

W. Hayduk

Method/Apparatus/Procedure:

The equipment essentially consisted of an autoclave immersed in a constant temperature bath and connected to a membrane pressure gauge.

Henry's constants for the lower pressure region and the solubilities for a pressure of 1 atm as estimated by the compiler are:
T/K H, atm \t x, mole fraction
263.15 \t 125 \t 0.00800
283.15 \t 225 \t 0.00444
303.15 \t 244 \t 0.00410
323.15 \t 286 \t 0.00351
353.15 \t 300 \t 0.00333
373.15 \t 313 \t 0.00319

Source and Purity of Materials:

The sources and purities of gas and solvent were not specified.

Estimated Errors:

Ambient temperature: δT/K = ±0.2
Mass concentration (m/v) (1): δx/mole fraction = ±0.002 (authors)
Pressure: δp/atm = ±0.05

Components:

Ethene, $\ce{ C2H4 }$; [74-85-1] NIST WebBook
Acetone, $\ce{ C3H6O }$; [67-64-1] NIST WebBook

Experimental Data

Henry's law is obeyed up to about 25 atm (2.53 MPa). The data were from the paper deposited in VINITI, Moscow.

Mole Fractions

$T$ ($\pu{K}$)	$T$ (°C)	$y_{1}$	$x_{1}$	$P$ ($\pu{atm}$)
263.15	-10	0.606	0.990	0.9494
263.15	-10	0.9494	0.010	0.9494
263.15	-10	0.0180	0.976	2.95
263.15	-10	0.9820	0.024	2.95
263.15	-10	0.0101	0.960	4.95
263.15	-10	0.9899	0.040	4.95
263.15	-10	2.1 x 10^-3	0.844	19.96
263.15	-10	0.9952	0.078	9.95
263.15	-10	4.8 x 10^-3	0.922	9.95
263.15	-10	0.9968	0.122	14.95
263.15	-10	3.2 x 10^-3	0.878	14.95
263.15	-10	0.9979	0.156	19.96
263.15	-10	1.4 x 10^-3	0.786	24.96
263.15	-10	0.9986	0.214	24.96
263.15	-10	9 x 10^-4	0.680	29.97
263.15	-10	0.9991	0.320	29.97
283.15	10	0.3983	0.995	0.6017
283.15	10	0.6017	5 x 10^-3	0.0617
283.15	10	0.0765	0.984	2.77
283.15	10	0.9235	0.016	2.77
283.15	10	0.0385	0.973	4.81
283.15	10	0.9616	0.027	4.81
283.15	10	0.0157	0.953	9.84
283.15	10	0.9843	0.047	9.84
283.15	10	0.0102	0.934	14.85
283.15	10	0.9898	0.066	14.85
283.15	10	7.0 x 10^-3	0.914	19.86
283.15	10	0.9930	0.086	19.86
283.15	10	5.3 x 10^-3	0.898	24.87
283.15	10	0.9947	0.102	24.87
283.15	10	4.3 x 10^-3	0.870	29.87
283.15	10	0.9957	0.130	29.87
283.15	10	3.7 x 10^-3	0.822	34.87
283.15	10	0.9963	0.178	34.87
303.15	30	0.4240	0.997	0.576
303.15	30	0.5760	3 x 10^-3	0.576
303.15	30	0.0744	0.984	2.78
303.15	30	0.9256	0.016	2.78
303.15	30	0.0410	0.978	4.80
303.15	30	0.9590	0.022	4.80
303.15	30	0.0194	0.960	9.81
303.15	30	0.9806	0.040	9.81
303.15	30	0.0115	0.946	14.83
303.15	30	0.9885	0.054	14.83
303.15	30	9.6 x 10^-3	0.924	19.81
303.15	30	0.9904	0.076	19.81
303.15	30	7.8 x 10^-3	0.896	24.81
303.15	30	0.9922	0.104	24.81
303.15	30	6.4 x 10^-3	0.878	29.81
303.15	30	0.9936	0.122	29.81
303.15	30	5.6 x 10^-3	0.854	34.80
303.15	30	0.9944	0.146	34.80
303.15	30	4.8 x 10^-3	0.824	39.81
303.15	30	0.9952	0.176	39.81
303.15	30	4.0 x 10^-3	0.794	44.82
303.15	30	0.9960	0.206	44.82
303.15	30	3.6 x 10^-3	0.764	49.82
303.15	30	0.9964	0.236	49.82
323.15	50	0.1518	0.993	2.54
323.15	50	0.8482	7 x 10^-3	2.54
323.15	50	0.0867	0.985	4.57
323.15	50	0.9133	0.015	4.57
323.15	50	0.0421	0.968	9.58
323.15	50	0.9579	0.032	9.58
323.15	50	0.0280	0.951	14.58
323.15	50	0.9720	0.049	14.58
323.15	50	0.0212	0.930	19.58
323.15	50	0.9831	0.070	19.58
323.15	50	0.0169	0.914	24.58
323.15	50	0.9880	0.086	24.58
323.15	50	0.0140	0.896	29.58
323.15	50	0.9860	0.104	29.58
323.15	50	0.0120	0.872	34.58
323.15	50	0.9880	0.128	34.58
323.15	50	0.0106	0.858	39.58
323.15	50	0.9894	0.142	39.58
323.15	50	9.6 x 10^-3	0.832	44.57
323.15	50	0.9904	0.168	44.57
323.15	50	8.7 x 10^-3	0.812	49.57
323.15	50	0.9913	0.188	49.57
323.15	50	8.0 x 10^-3	0.788	54.56
323.15	50	0.9920	0.212	54.56
323.15	50	7.4 x 10^-3	0.764	59.56
323.15	50	0.9926	0.236	59.56
353.15	80	0.2971	0.988	3.51
353.15	80	0.7029	0.012	3.51
353.15	80	0.1339	0.974	8.66
353.15	80	0.8661	0.026	8.66
353.15	80	0.0890	0.956	13.67
353.15	80	0.9110	0.044	13.67
353.15	80	0.0653	0.940	18.69
353.15	80	0.9347	0.060	18.69
353.15	80	0.0532	0.920	23.67
353.15	80	0.9468	0.080	23.67
353.15	80	0.0440	0.904	28.68
353.15	80	0.9560	0.096	28.68
353.15	80	0.0379	0.886	33.67
353.15	80	0.9621	0.114	33.67
353.15	80	0.0326	0.864	38.70
353.15	80	0.9674	0.136	38.70
353.15	80	0.0298	0.854	43.66
353.15	80	0.9702	0.146	43.66
353.15	80	0.0270	0.832	48.65
353.15	80	0.9730	0.168	48.65
353.15	80	0.0242	0.812	53.67
353.15	80	0.9758	0.188	53.67
353.15	80	0.0228	0.800	58.63
353.15	80	0.9772	0.200	58.63
353.15	80	0.0212	0.772	63.62
353.15	80	0.9788	0.228	63.62
353.15	80	0.0197	0.766	68.62
353.15	80	0.9803	0.234	68.62
353.15	80	0.0185	0.748	73.61
353.15	80	0.9815	0.252	73.61
373.15	100	0.6280	0.997	1.86
373.15	100	0.3720	3 x 10^-3	1.86
373.15	100	0.2634	0.980	7.37
373.15	100	0.7366	0.020	7.37
373.15	100	0.1676	0.962	12.49
373.15	100	0.8324	0.038	12.49
373.15	100	0.1234	0.946	17.53
373.15	100	0.8766	0.054	17.53
373.15	100	0.1090	0.928	22.28
373.15	100	0.8910	0.072	22.28
373.15	100	0.0822	0.912	27.53
373.15	100	0.9178	0.088	27.53
373.15	100	0.0710	0.894	32.52
373.15	100	0.9290	0.106	32.52
373.15	100	0.0621	0.876	37.52
373.15	100	0.9379	0.124	37.52
373.15	100	0.0553	0.856	42.51
373.15	100	0.9447	0.144	42.51
373.15	100	0.0500	0.844	47.50
373.15	100	0.9500	0.156	47.50
373.15	100	0.0458	0.832	52.48
373.15	100	0.9542	0.168	52.48
373.15	100	0.0423	0.812	57.46
373.15	100	0.9577	0.188	57.46
373.15	100	0.0392	0.790	62.45
373.15	100	0.9608	0.210	62.45
373.15	100	0.0366	0.776	67.44
373.15	100	0.9634	0.224	67.44

(1) Calculated by the compiler.

IUPAC-NIST Solubility Data Series, SRD 106