NIST-IUPAC Solubility Data Series

Ethene with 2-Propanone (IUPAC SDS Volume 57)

SDS Volume

Volume 57. Ethene, p 296

Source Publication

Voronkov, A. P.; Mislavskaya, V. S.; Mushii, R. Ya.; Drygina, V. V.; Zh. Prikl. Khim. 1979, 52, 2642.

Conditions:

Room Temp: 263.15 - 373.15 $\pu{K}$
Pressure: 0.101 - 7.60 $\pu{MPa}$

Compiler:

W. Hayduk

Methodology:

The equipment essentially consisted of an autoclave immersed in a constant temperature bath and connected to a membrane pressure gauge.

Henry's constants for the lower pressure region and the solubilities for a pressure of 1 atm as estimated by the compiler are:
T/K H, atm \t x, mole fraction
263.15 \t 125 \t 0.00800
283.15 \t 225 \t 0.00444
303.15 \t 244 \t 0.00410
323.15 \t 286 \t 0.00351
353.15 \t 300 \t 0.00333
373.15 \t 313 \t 0.00319

Sample Information:

The sources and purities of gas and solvent were not specified.

Measurement Errors:

Ambient temperature: δT/K = ±0.2
Mass concentration (m/v) (1): δx/mole fraction = ±0.002 (authors)
Pressure: δp/atm = ±0.05

System Components:

Ethene, $\ce{ C2H4 }$; [74-85-1] NIST WebBook
Acetone, $\ce{ C3H6O }$; [67-64-1] NIST WebBook

Experimental Data

Henry's law is obeyed up to about 25 atm (2.53 MPa). The data were from the paper deposited in VINITI, Moscow.

$T$ ($\pu{K}$)	$T$ (°C)	$y_{1}$	$x_{1}$	$P$ ($\pu{atm}$)
263.15	-10	0.606¹	0.990¹	0.9494¹
263.15	-10	0.9494	0.010¹	0.9494¹
263.15	-10	0.0180¹	0.976¹	2.95¹
263.15	-10	0.9820	0.024¹	2.95¹
263.15	-10	0.0101¹	0.960¹	4.95¹
263.15	-10	0.9899	0.040¹	4.95¹
263.15	-10	2.1 x 10^-3¹	0.844¹	19.96¹
263.15	-10	0.9952	0.078¹	9.95¹
263.15	-10	4.8 x 10^-3¹	0.922¹	9.95¹
263.15	-10	0.9968	0.122¹	14.95¹
263.15	-10	3.2 x 10^-3¹	0.878¹	14.95¹
263.15	-10	0.9979	0.156¹	19.96¹
263.15	-10	1.4 x 10^-3¹	0.786¹	24.96¹
263.15	-10	0.9986	0.214¹	24.96¹
263.15	-10	9 x 10^-4¹	0.680¹	29.97¹
263.15	-10	0.9991	0.320¹	29.97¹
283.15	10	0.3983¹	0.995¹	0.6017¹
283.15	10	0.6017	5 x 10^-3¹	0.0617¹
283.15	10	0.0765¹	0.984¹	2.77¹
283.15	10	0.9235	0.016¹	2.77¹
283.15	10	0.0385¹	0.973¹	4.81¹
283.15	10	0.9616	0.027¹	4.81¹
283.15	10	0.0157¹	0.953¹	9.84¹
283.15	10	0.9843	0.047¹	9.84¹
283.15	10	0.0102¹	0.934¹	14.85¹
283.15	10	0.9898	0.066¹	14.85¹
283.15	10	7.0 x 10^-3¹	0.914¹	19.86¹
283.15	10	0.9930	0.086¹	19.86¹
283.15	10	5.3 x 10^-3¹	0.898¹	24.87¹
283.15	10	0.9947	0.102¹	24.87¹
283.15	10	4.3 x 10^-3¹	0.870¹	29.87¹
283.15	10	0.9957	0.130¹	29.87¹
283.15	10	3.7 x 10^-3¹	0.822¹	34.87¹
283.15	10	0.9963	0.178¹	34.87¹
303.15	30	0.4240¹	0.997¹	0.576¹
303.15	30	0.5760	3 x 10^-3¹	0.576¹
303.15	30	0.0744¹	0.984¹	2.78¹
303.15	30	0.9256	0.016¹	2.78¹
303.15	30	0.0410¹	0.978¹	4.80¹
303.15	30	0.9590	0.022¹	4.80¹
303.15	30	0.0194¹	0.960¹	9.81¹
303.15	30	0.9806	0.040¹	9.81¹
303.15	30	0.0115¹	0.946¹	14.83¹
303.15	30	0.9885	0.054¹	14.83¹
303.15	30	9.6 x 10^-3¹	0.924¹	19.81¹
303.15	30	0.9904	0.076¹	19.81¹
303.15	30	7.8 x 10^-3¹	0.896¹	24.81¹
303.15	30	0.9922	0.104¹	24.81¹
303.15	30	6.4 x 10^-3¹	0.878¹	29.81¹
303.15	30	0.9936	0.122¹	29.81¹
303.15	30	5.6 x 10^-3¹	0.854¹	34.80¹
303.15	30	0.9944	0.146¹	34.80¹
303.15	30	4.8 x 10^-3¹	0.824¹	39.81¹
303.15	30	0.9952	0.176¹	39.81¹
303.15	30	4.0 x 10^-3¹	0.794¹	44.82¹
303.15	30	0.9960	0.206¹	44.82¹
303.15	30	3.6 x 10^-3¹	0.764¹	49.82¹
303.15	30	0.9964	0.236¹	49.82¹
323.15	50	0.1518¹	0.993¹	2.54¹
323.15	50	0.8482	7 x 10^-3¹	2.54¹
323.15	50	0.0867¹	0.985¹	4.57¹
323.15	50	0.9133	0.015¹	4.57¹
323.15	50	0.0421¹	0.968¹	9.58¹
323.15	50	0.9579	0.032¹	9.58¹
323.15	50	0.0280¹	0.951¹	14.58¹
323.15	50	0.9720	0.049¹	14.58¹
323.15	50	0.0212¹	0.930¹	19.58¹
323.15	50	0.9831	0.070¹	19.58¹
323.15	50	0.0169¹	0.914¹	24.58¹
323.15	50	0.9880	0.086¹	24.58¹
323.15	50	0.0140¹	0.896¹	29.58¹
323.15	50	0.9860	0.104¹	29.58¹
323.15	50	0.0120¹	0.872¹	34.58¹
323.15	50	0.9880	0.128¹	34.58¹
323.15	50	0.0106¹	0.858¹	39.58¹
323.15	50	0.9894	0.142¹	39.58¹
323.15	50	9.6 x 10^-3¹	0.832¹	44.57¹
323.15	50	0.9904	0.168¹	44.57¹
323.15	50	8.7 x 10^-3¹	0.812¹	49.57¹
323.15	50	0.9913	0.188¹	49.57¹
323.15	50	8.0 x 10^-3¹	0.788¹	54.56¹
323.15	50	0.9920	0.212¹	54.56¹
323.15	50	7.4 x 10^-3¹	0.764¹	59.56¹
323.15	50	0.9926	0.236¹	59.56¹
353.15	80	0.2971¹	0.988¹	3.51¹
353.15	80	0.7029	0.012¹	3.51¹
353.15	80	0.1339¹	0.974¹	8.66¹
353.15	80	0.8661	0.026¹	8.66¹
353.15	80	0.0890¹	0.956¹	13.67¹
353.15	80	0.9110	0.044¹	13.67¹
353.15	80	0.0653¹	0.940¹	18.69¹
353.15	80	0.9347	0.060¹	18.69¹
353.15	80	0.0532¹	0.920¹	23.67¹
353.15	80	0.9468	0.080¹	23.67¹
353.15	80	0.0440¹	0.904¹	28.68¹
353.15	80	0.9560	0.096¹	28.68¹
353.15	80	0.0379¹	0.886¹	33.67¹
353.15	80	0.9621	0.114¹	33.67¹
353.15	80	0.0326¹	0.864¹	38.70¹
353.15	80	0.9674	0.136¹	38.70¹
353.15	80	0.0298¹	0.854¹	43.66¹
353.15	80	0.9702	0.146¹	43.66¹
353.15	80	0.0270¹	0.832¹	48.65¹
353.15	80	0.9730	0.168¹	48.65¹
353.15	80	0.0242¹	0.812¹	53.67¹
353.15	80	0.9758	0.188¹	53.67¹
353.15	80	0.0228¹	0.800¹	58.63¹
353.15	80	0.9772	0.200¹	58.63¹
353.15	80	0.0212¹	0.772¹	63.62¹
353.15	80	0.9788	0.228¹	63.62¹
353.15	80	0.0197¹	0.766¹	68.62¹
353.15	80	0.9803	0.234¹	68.62¹
353.15	80	0.0185¹	0.748¹	73.61¹
353.15	80	0.9815	0.252¹	73.61¹
373.15	100	0.6280¹	0.997¹	1.86¹
373.15	100	0.3720	3 x 10^-3¹	1.86¹
373.15	100	0.2634¹	0.980¹	7.37¹
373.15	100	0.7366	0.020¹	7.37¹
373.15	100	0.1676¹	0.962¹	12.49¹
373.15	100	0.8324	0.038¹	12.49¹
373.15	100	0.1234¹	0.946¹	17.53¹
373.15	100	0.8766	0.054¹	17.53¹
373.15	100	0.1090¹	0.928¹	22.28¹
373.15	100	0.8910	0.072¹	22.28¹
373.15	100	0.0822¹	0.912¹	27.53¹
373.15	100	0.9178	0.088¹	27.53¹
373.15	100	0.0710¹	0.894¹	32.52¹
373.15	100	0.9290	0.106¹	32.52¹
373.15	100	0.0621¹	0.876¹	37.52¹
373.15	100	0.9379	0.124¹	37.52¹
373.15	100	0.0553¹	0.856¹	42.51¹
373.15	100	0.9447	0.144¹	42.51¹
373.15	100	0.0500¹	0.844¹	47.50¹
373.15	100	0.9500	0.156¹	47.50¹
373.15	100	0.0458¹	0.832¹	52.48¹
373.15	100	0.9542	0.168¹	52.48¹
373.15	100	0.0423¹	0.812¹	57.46¹
373.15	100	0.9577	0.188¹	57.46¹
373.15	100	0.0392¹	0.790¹	62.45¹
373.15	100	0.9608	0.210¹	62.45¹
373.15	100	0.0366¹	0.776¹	67.44¹
373.15	100	0.9634	0.224¹	67.44¹

(1) Calculated by the compiler.

IUPAC-NIST Solubility Data Series, SRD 106