SDS Volume
Volume 57. Ethene, p 285
Source Publication
Conditions:
Room Temp:
273.15 - 303.15
$\pu{K}$
Pressure:
101.32
$\pu{kPa}$
Compiler:
Methodology:
The experimental apparatus and method is described elsewhere [1]. It consists of a system of burette, a mercury manometer and a solution vessel. The mole fraction of the dissolved gas is estimated from the volume change at constant pressure of saturated gas in the burettes, and the mass of the solvent in the solution vessel determined by weighing.
The vapor pressure of the solvent was measured and fitted to the following equation: $$\ln(P_{2}/\pu{kPa}) = -5552.37 (T/\pu{K})^{-1} + 18.046$$
Sample Information:
- Ethene. Sociedad Español del Oxigeno. Specified purity 99.9%.
- 2-Methylcyclohexanone. Merck. Purity checked by GLC to be ≥ 98.1%.
Measurement Errors:
Ambient temperature: δT/K = ±0.2
Mass concentration (m/v) (1): δx1/x1 = ±0.007 (authors)
Methodology Citation
System Components:
- Ethene, $\ce{ C2H4 }$; [74-85-1] NIST WebBook
- 2-Methylcyclohexanone, $\ce{ C7H12O }$; [583-60-8] NIST WebBook
Experimental Data
The authors fitted their data to the equation: $$-\ln x_{1} = 8.3232 - 1190.24 (T/\pu{K})^{-1}$$ They also obtained $\Delta H/\pu{kJ mol-1} = -9.9$ and $\Delta S/\pu{J K-1 mol-1} = -69$ for the transfer of one mole of ethene from the gas phase at $\pu{101.32 kPa}$ to the hypothetical unit mole fraction solution.
| $T$ ($\pu{K}$) | $x_{1}$ | $L$ | α ($\pu{cm3(g) cm-3(l) atm-1}$) |
|---|---|---|---|
| 273.15 | 0.0188 | 3.5801 | 3.5801 |
| 283.15 | 0.0164 | 3.2051 | 3.0901 |
| 293.15 | 0.01407 | 2.8151 | 2.6201 |
| 298.15 | 0.01315 | 2.6601 | 2.4351 |
| 303.15 | 0.01228 | 2.5151 | 2.2651 |
(1) The Bunsen and Ostwald coefficients were calculated by the compiler.
