Compilation - Ethene with Ethane, 1,1,2-trichloro-1,2,2-trifluoro- (Freon 113) (IUPAC SDS Volume 57)
SDS Volume (1221)
Volume 57. Ethene, p None
Original Measurements
Sokolov, Yu. P.; Konshin, A. I.; Zh. Prikl. Khim. 1989, 62, 1395-1398.
Variables:
Room Temp:
300.15 - 363.15
$\pu{K}$
Pressure:
0.20 - 1.11
Prepared by:
Method/Apparatus/Procedure:
The solubilities were measured using a stirred reactor with a magnetic drive having a volume of 250 mL and equipped with a pressure gauge and a surrounding jacket for temperature control. Gas and sample handling systems were attached. A volume of 100-200 mL of deaerated solvent was charged to the reactor and equilibrated. A small liquid sample chamber was used to confine a known volume of saturated solution. The sample was then completely evaporated into a much larger vessel. Helium carrier gas was used to increase the pressure of the vapor gas mixture to about 0.12 MPs. The sample was then analyzed by gas chromatography. Details are in [1].
Source and Purity of Materials:
- No information about gas or solvent source or purity was supplied.
Estimated Errors:
Mass concentration (m/v) (1): δC1 = ±3% (complier)
Components:
- Ethene, $\ce{ C2H4 }$; [74-85-1] NIST WebBook
- 1,1,2-Trichloro-1,2,2-trifluoroethane, $\ce{ C2Cl3F3 }$; [76-13-1] NIST WebBook
Experimental Data
| $T$ ($\pu{K}$) | $T$ (°C) | $x_{1}$ | $P$ ($\pu{MPa}$) | $k_{\rm{D}}$ ($\pu{MPa-1}$) | $C_{\rm{H}}^{\prime}$ (mol/L) |
|---|---|---|---|---|---|
| 300.15 | 27 | 0.029 | 0.20 | 5.33 | 0.25 |
| 300.15 | 27 | 0.054 | 0.31 | - | 0.47 |
| 300.15 | 27 | 0.095 | 0.51 | - | 0.87 |
| 300.15 | 27 | 0.154 | 0.71 | - | 1.51 |
| 343.15 | 70 | 0.010 | 0.31 | 7.91 | 0.08 |
| 343.15 | 70 | 0.037 | 0.51 | - | 0.29 |
| 343.15 | 70 | 0.064 | 0.71 | - | 0.51 |
| 343.15 | 70 | 0.097 | 0.91 | - | 0.79 |
| 343.15 | 70 | 0.123 | 1.11 | - | 1.01 |
| 363.15 | 90 | 0.015 | 0.51 | 9.15 | 0.11 |
| 363.15 | 90 | 0.040 | 0.71 | - | 0.30 |
| 363.15 | 90 | 0.062 | 0.91 | - | 0.47 |
| 363.15 | 90 | 0.083 | 1.11 | - | 0.64 |
(1) Calculated by the compiler.
(2) Stated by authors to be lim x1→o(p1/x1) for p1 = partial pressure of gas.
